SOCAR Proceedings

SOCAR Proceedings

Published by "OilGasScientificResearchProject" Institute of State Oil Company of Azerbaijan Republic (SOCAR).

SOCAR Proceedings is published from 1930 and is intended for oil and gas industry specialists, post-graduate (students) and scientific workers.

Journal is indexed in Web of Science (Emerging Sources Citation Index), SCOPUS and Russian Scientific Citation Index, and abstracted in EI’s Compendex, Petroleum Abstracts (Tulsa), Inspec, Chemical Abstracts database.

A.V.Osipov1, V.Yu.Kerimov2, E.I.Vasilenko1, A.S.Monakova1

1Gubkin Russian State University of Oil and Gas (National Research University), Moscow, Russia; 2The Russian State Geological Prospecting University named after Sergo Ordzhonikidze, Moscow, Russia

Petroleum systems formation conditions in the deeply sediments in the south-east part of the Volga-Ural oil and gas province


The article considers formation conditions of oil and gas potential and evaluated the prospects of searching of oil and gas accumulations in deep-lying (5 km and more) sediments of the south-eastern part of the Volga-Ural oil and gas province (Russian Federation) based on a complex analysis of geological, geophysical and geochemical studies and modeling of petroleum systems. Falling production of hydrocarbons in large fields and the depletion of the hydrocarbon resource in the Volga-Ural province make the problem of searching new exploration objects in deep sediments relevant. In this work, the elements and processes of deep-lying petroleum systems are studied, the catagenesis of organic matter of rocks is determined, the generation scale is shown, the time of trap formation is established, which allowed us to create the criteria base for predicting the oil and gas content of the sediments studied. The most promising local sites for searching of oil and gas accumulations at great depths within the south-eastern part of the Volga-Ural oil and gas province are identified.

Keywords: abnormally high pore pressures; great depths; Volga-Ural oil and gas province; gas; modeling; source rock; oil; organic matter; source of generation; petroleum systems.

The article considers formation conditions of oil and gas potential and evaluated the prospects of searching of oil and gas accumulations in deep-lying (5 km and more) sediments of the south-eastern part of the Volga-Ural oil and gas province (Russian Federation) based on a complex analysis of geological, geophysical and geochemical studies and modeling of petroleum systems. Falling production of hydrocarbons in large fields and the depletion of the hydrocarbon resource in the Volga-Ural province make the problem of searching new exploration objects in deep sediments relevant. In this work, the elements and processes of deep-lying petroleum systems are studied, the catagenesis of organic matter of rocks is determined, the generation scale is shown, the time of trap formation is established, which allowed us to create the criteria base for predicting the oil and gas content of the sediments studied. The most promising local sites for searching of oil and gas accumulations at great depths within the south-eastern part of the Volga-Ural oil and gas province are identified.

Keywords: abnormally high pore pressures; great depths; Volga-Ural oil and gas province; gas; modeling; source rock; oil; organic matter; source of generation; petroleum systems.

References

  1. 1. S.E.Bashkova, T.V.Karaseva. The forecast of oil-andgas content of the deep horizons of the Volga-Ural NGP //Geology, Geophysics and Development of Oil and Gas Fields. -2015. –No. 11. -P.9-14. 
  2. A.L.Lapidus, V.Y.Kerimov, R.N.Mustaev, et al. Caucasus Maykopian kerogenous shale sequences: Generative potential //Oil Shale. -2018. -No.35(2). -P.113-127. 
  3. I.V.Golovanova. Teplovoe pole yuzhnogo Urala. Dissertaciya na soiskanie uchenoj stepeni doktora fizikomatematicheskih nauk. Ufa: RAN Ufimskij nauchnyj centr, Institut geologii, 2003. 
  4. I.V.Golovanova, R.Ju.Sal'manova. Analiz dannyh po teplovomu potoku Urala //Geologicheskij sbornik. -2008. -№7. - S. 233-239. 
  5. V.E.Sal'nikov. Geotermicheskij rezhim juzhnogo Urala. M.: Nauka, 1984. 
  6. A . P . V i n o g r a d o v . A t l a s l i t o l o g o - paleogeograficheskih kart SSSR. M.: Ministerstvo geologii SSSR, 1968. 
  7. B.P.Wygrala. Integrated study of an oil field in the southern Po basin, Northern Italy. Ph.D dissertation. Köln University: Jülich, Research Centre Jülich, 1989. 
  8. V.Yu.Kerimov, G.N.Gordadze, R.N.Mustaev, A.V.Bondarev. Formation conditions of hydrocarbon systems on the Sakhalin shelf of the sea of okhotsk based on the geochemical studies and modeling //Oriental Journal of Chemistry. -2018 -No.34(2). -P.934-947. 
  9. I.S.Guliyev, V.Yu.Kerimov, A.V.Osipov, R.N.Mustaev. Generation and accumulation of hydrocarbons at great depths under the Earth’s crust //SOCAR Proceedings. -2017. -№1. -P. 4-16. 
  10. V.Yu.Kerimov, A.V.Bondarev, R.N.Mustaev, V.N.Khoshtaria. Estimation of geological risks in searching and exploration of hydrocarbon deposits //Oil Industry. -2017. –No.8. -P. 36-41. 
  11. V . Y u . K e r i m o v , A . V . B o n d a r e v , A . V . O s i p o v , S . G . S e r o v . E v o l u t i o n o f p e t r o l e u m s y s t e m s i n the territory of Baikit anticlise and Kureiskaya syneclise (Eastern Siberia) //Oil Industry. -2015. –No.5. -P. 39-42. 
  12. V . Y u . K e r i m o v , A . A . G o r b u n o v , E . A . L a v r e n o v a , A . V . O s i p o v . M o d e l s o f h y d r o c a r b o n s y s t e m s i n t h e R u s s i a n P l a t f o r m – U r a l j u n c t i o n z o n e / / L i t h o l o g y a n d M i n e r a l R e s o u r c e s . - 2 0 1 5 . - V o l . 5 0 . – N o . 5 . - P . 3 9 4 - 4 0 6 .
  13. V.Yu.Kerimov, N.B.Kuznetsov, R.N.Mustaev, et al. Conditions for hydrocarbon deposits formation in the uplift-thrust structures of the eastern side of the Pre-Ural fore deep //Oil Industry. -2017. –No. 7. -P. 36-41. 
  14. R.N.Mustaev, W.N.Hai, V.Y.Kerimov, E.A.Leonova. Generation and conditions formation of hydrocarbon deposits in kyulong basin by simulation results hydrocarbon systems //Geomodel 2015 - 17th Scientific-
    Practical Conference on Oil and Gas Geological Exploration and Development. -P. 212-216. 
  15. R.N.Mustaev, V.Y.Kerimov, G.Y.Shilov, S.S.Dmitrievsky. Modeling of thermobaric conditions formation of the shale hydrocarbon accumulations in low-permeability reservoirs khadum formation ciscaucasia //Geomodel 2016 - 18th Science and Applied Research Conference on Oil and Gas Geological Exploration and Development. 
  16. V.Yu.Kerimov, R.N.Mustaev, N.Sh.Yandarbiev, E.M.Movsumzade. Environment for the Formation of Shale Oil and Gas Accumulations in Low-Permeability Sequences of the Maikop Series, Fore-Caucasus //Oriental Journal of Chemistry. -2017. -Vol. 33. -№2. -P. 879-892. 
  17. V.Yu.Kerimov, A.V.Osipov, E.A.Lavrenova. The hydrocarbon potential of deep horizons in the southeastern part of the Volga-Urals oil and gas province //Oil Industry. -2014. –No.4. -P. 33-35 
  18. V.Yu.Kerimov, A.V.Osipov, A.S.Nefedova. Hydrocarbon systems of the Pre-Ural fore deep //Oil Industry. -2017. –No.4. -P. 36-40. 
  19. V.Yu.Kerimov, M.Z.Rachinsky, R.N.Mustaev, A.V.Osipov. Groundwater Dynamics Forecasting Criteria of Oil and Gas Occurrences in Alpine Mobile Belt Basins //Doklady Earth Sciences. -2017. -Vol. 476. -Part 1. -P. 1066–1068. 
  20. V.Yu.Kerimov, E.I.Vasilenko, A.V.Osipov, G.Y.Shilov. Evaluation of geo-fluid and abnormally high reservoir (pore) pressures of sedimentary complex of southern part of Pre-Ural fore deep //Oil Industry.
    -2017. –No. 5. -P. 22-26. 
  21. A.V.Osipov, A.S.Monakova, M.V.Zakharchenko, R.N.Mustaev. Assessment of Caprock Fluid-Resistive Characteristics of Pre-Urals Fore Deep Southern Part // Proceedings of the 17th Scientific-Practical Conference on Oil and Gas Geological Exploration and Development - «Geomodel 2015». Gelendzhik, 2015. - P. 1-4. M.Z.Rachinsky, V.Yu.Kerimov. Fluid dynamics of oil and gas reservoirs. USA: Scrivener Publishing Wiley, 2015.- P. 1-4. 
  22. M.Z.Rachinsky, V.Yu.Kerimov. Fluid dynamics of oil and gas reservoirs. USA: Scrivener Publishing Wiley, 2015.
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DOI: 10.5510/OGP20190100374

E-mail: osipov.a@gubkin.ru


B.A.Suleimanov1, Y.A.Latifov2, E.F.Veliyev1

1«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan; 2SOCAR, Baku, Azerbaijan

Softened water application for enhanced oil recovery


This paper discusses the application of low hardness alkali water compositions (LHAW) as a secondary and tertiary displacement agent for EOR. A comparative analysis of the impact of low salinity water (LSW) and LHAW water on interfacial tension, contact angle on rock, adsorption of ions, emulsion stability and clay swelling is presented. LHAW application contributes to the formation of stable water in oil (w/o) emulsions
and a decrease in clay swelling compared to LSW. Adsorption values for both fluids are similar. Contact angle measurements show that both LSW and LHAW reduce interfacial tension compared to Synthetic Caspian Sea water (SCSW), by up to 17% and 94% respectively. Similar results were observed for contact angle measurements. Flooding experiments were conducted in secondary and tertiary modes. In secondary flooding the two water compositions LHAW-2 and LHAW-1 increased the oil recovery (%OOIP) in comparison with SCSW at water breakthrough, by 29% and 25% respectively. The final oil recovery increases were 21% and 15% respectively. In tertiary flooding, tests showed that LHAW-2 and LHAW-1 oil recoveries (%OOIP) compared to LSW were 13% and 10% respectively. The oil recovery rate for LHAW solutions was not linear versus lnt as was that for LSW. This was proposed as a consequence of emulsions generation while water-cut is below 50% however, above 50% water cut the rate stabilizes.

Keywords: EOR; Low hardness alkali water; Sandstone flooding; Bentonite swelling; Low salinity water; Emulsion.

This paper discusses the application of low hardness alkali water compositions (LHAW) as a secondary and tertiary displacement agent for EOR. A comparative analysis of the impact of low salinity water (LSW) and LHAW water on interfacial tension, contact angle on rock, adsorption of ions, emulsion stability and clay swelling is presented. LHAW application contributes to the formation of stable water in oil (w/o) emulsions
and a decrease in clay swelling compared to LSW. Adsorption values for both fluids are similar. Contact angle measurements show that both LSW and LHAW reduce interfacial tension compared to Synthetic Caspian Sea water (SCSW), by up to 17% and 94% respectively. Similar results were observed for contact angle measurements. Flooding experiments were conducted in secondary and tertiary modes. In secondary flooding the two water compositions LHAW-2 and LHAW-1 increased the oil recovery (%OOIP) in comparison with SCSW at water breakthrough, by 29% and 25% respectively. The final oil recovery increases were 21% and 15% respectively. In tertiary flooding, tests showed that LHAW-2 and LHAW-1 oil recoveries (%OOIP) compared to LSW were 13% and 10% respectively. The oil recovery rate for LHAW solutions was not linear versus lnt as was that for LSW. This was proposed as a consequence of emulsions generation while water-cut is below 50% however, above 50% water cut the rate stabilizes.

Keywords: EOR; Low hardness alkali water; Sandstone flooding; Bentonite swelling; Low salinity water; Emulsion.

References

  1. J.C.Martin. The effects of clay on the displacement of heavy oil by water //Paper SPE-1411-G presented at the SPE Venezuelan Annual Meeting, Caracas, Venezuela, 14-16 October 1959. 
  2. G.G.Bernard. Effect of floodwater salinity on recovery of oil from cores containing clays //Paper SPE-1725-MS presented at the SPE California Regional Meeting, Los Angeles, California, 26-27 October 1967.
  3. N.R.Morrow, G.Q.Tang, M.Valat, X.Xie. Prospects of improved oil recovery related to wettability and brine composition //Journal of Petroleum Science and Engineering. - 1998. - Vol.20. - P. 267-276. 
  4. J.S.Buckley. Mechanisms and consequences of wettability alteration by crude oils [dissertation]. Heriot-Watt University Petroleum Engineering; 1996. 
  5. K.Webb, C.Black, H.Al-Ajeel. Low salinity oil recovery log-inject-log //Paper SPE-89379-MS presented at the SPE/DOE Symposium on Improved Oil Recovery, Tulsa, Oklahoma, USA, 17-21 April 2004. 
  6. J.Seccombe, A.Lager, G.Jerauld, et al. Demonstration of low-salinity EOR at interwell-scale, Endicott field, Alaska //Paper SPE-129692-MS presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 24-28 April 2010. 
  7. K.Skrettingland, T.Holt, M.T.Tweheyo, I.Skjevrak. Snorre low-salinity-water injection-coreflooding experiments and single-well field pilot //SPE Reservoir Evaluation and Engineering. -2010. -Vol. 14. -P.182-192. 
  8. F.F.Abdulla, H.S.Hashem, A.Abdulraheem, et al. First EOR trial using low salinity water injection in the greater, Burgan field, Kuwait //Paper SPE-164341-MS presented at the SPE Middle East Oil and Gas
    Show and Conference, Manama, Bahrain, 10-13 March 2013. 
  9. P.Jadhunandan, N.Morrow. Effect of wettability on waterflooding recovery for crude oil/brine/rock systems //SPE Reservoir Engineering. -1995. -Vol. 10. -P. 40-46. 
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  11. N.Loahardjo, X.Xie, P.Yin, N.R.Morrow. Low salinity waterflooding of a reservoir rock //Paper SCA2007-29 presented at the International Symposium of the Society of Core Analysts, Canada, Calgary, 10-12 September 2007. 
  12. M.Cissokho, S.Boussour, P.Cordier, et al. Low salinity oil recovery on clayey sand-stone: Experimental study //Journal of Petrophysics. -2010. -Vol. 51. -P. 305-313. 
  13. S.Rivet, L.Lake, G.Pope. A coreflood investigation of low-salinity enhanced oil recovery //Paper SPE-134297-MS presented at the SPE Annual Technical Conference and Exhibition, Florence, Italy, 19-22
    September 2010. 
  14. T.Austad, A.RezaeiDoust, T.Puntervold. Chemical mechanism of low salinity water flooding in sandstone reservoirs //Paper SPE-129767-MS presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 24-28 April 2010. 
  15. A.Yousef Ali, S.Al-Saleh, M.Al-Jawfi. Improved/enhanced oil recovery from carbonate reservoirs by tuning injection water salinity and ionic content //Paper SPE-154076-MS presented at the SPE Improved
    Oil Recovery Symposium, Tulsa, Oklahoma, USA, 14-18 April 2012. 
  16. B.A.Suleimanov, Y.A.Latifov, E.F.Veliyev, H.Frampton. Comparative analysis of the EOR mechanisms by using low salinity and low hardness alkaline water //Journal of Petroleum Science and Engineering.
    -2018. -Vol. 162. -P.35-43. 
  17. P.Zhang, M.T.Tweheyo, T.Austad. Wettability alteration and improved oil recovery byspontaneous imbibition of seawater into chalk: Impact of the potential determining ions Ca2+, Mg2+, and SO42- //Colloids
    and Surfaces A: Physicochemical and Engineering Aspects. -2007. -Vol.301. -P.199-208. 
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    November 2005. 
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  21. K.Spildo, A.Skauge, T.Skauge. Propagation of colloidal dispersion gels (CDG) in laboratory corefloods //Paper SPE-129927-MS presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 24-28 April 2010. 
  22. D.J.Ligthelm, J.Gronsveld, J.P.Hofman, et al. Novel waterflooding strategy by manipulation of injection brine composition //Paper presented at the EUROPEC/EAGE Conference and Exhibition, Amsterdam, The Netherlands, 8-11 June 2009. 
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  24. W.G.Anderson. Wettability literature survey - Part 1: Rock/oil/brine interactions and the effects of core handling on wettability //SPE Journal of Petroleum Technology. - 1986. - Vol. 38. - Issue 10.
  25. J.M.Jacobson, J.H.Frenz, C.Horvath. Measurement of competitive adsorption isotherms by frontal chromatography //Industrial & Engineering Chemistry Research. -1987. -Vol.26. -P.43-50.
  26. API RP40. Recommended practices for core analysis. Second Edition. American Petroleum Institute, 1998. 
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    Houston, Texas, USA, 3-6 October 1999. 
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  29. A.M.O.Mohamed, M. el Gamal, A.Y.Zekri. Effect of salinity and temperature on water cut determination in oil reservoirs //Journal of Petroleum Science and Engineering. -2003. -Vol. 40. -P.177-188.
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  31. H. van Olphen. An introduction to clay colloid chemistry. 2nd Ed. New York: Wiley, 1997.
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  33. S.Suzuki, S.Prayongphan, Y.Ichikawa, BG.Chae. Swelling of bentonite in contact with NaCl solutions by using the confocal laser scanning microscope //Applied Clay Science. -2005. -Vol. 29. -P.89-98.
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DOI: 10.5510/OGP20190100375

E-mail: baghir.suleymanov@socar.az


F.G.Hasanov

«OilGasScientificResearchProject» Institute, Baku, Azerbaijan

Study of separation system in oil and gas production


As an extension of the pipeline in the direction of the flowstream, there must be installed a condensate accumulating ank serving as a trap downstream the separation unit to get mechanical solid particles and condensate accumulated and have them separated due to their mechanical energy with regard to special mass from the transported gas in gas production and the gas flow stream should be rerouted by three-way valve upstream the tank.In oil production, in order to perform the separation of the mechanical solid particles in the composition of oil due to special mass difference thanks to their mechanical energy and their accumulation, a vertical tank serving as a trap should be installed on the extension of oil reservoir upstream the oil and gas separator and the oil flow direction must be rerouted towards the oil and gas separator by the three-way valve upstream the tank.

Keywords: gas separator; oil&gas separator; condensate; mechanical solid particles; screen; condensate accumulating tank; density.

As an extension of the pipeline in the direction of the flowstream, there must be installed a condensate accumulating ank serving as a trap downstream the separation unit to get mechanical solid particles and condensate accumulated and have them separated due to their mechanical energy with regard to special mass from the transported gas in gas production and the gas flow stream should be rerouted by three-way valve upstream the tank.In oil production, in order to perform the separation of the mechanical solid particles in the composition of oil due to special mass difference thanks to their mechanical energy and their accumulation, a vertical tank serving as a trap should be installed on the extension of oil reservoir upstream the oil and gas separator and the oil flow direction must be rerouted towards the oil and gas separator by the three-way valve upstream the tank.

Keywords: gas separator; oil&gas separator; condensate; mechanical solid particles; screen; condensate accumulating tank; density.

References

  1. T.M.Bekirov, A.T.Shatalov. Collecting and preparing the natural gas to transport. M.: Nedra, 1986. 
  2. V.P.Demkov, O.N.Tretyakova. Physics. Theory. Method. Tasks. M.: Higher school, 2001. 
  3. A.S.Smirnov, A.I.Shirkovskij. Gas production and transportation. M.: Gostoptekhizdat, 1957.
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DOI: 10.5510/OGP20190100376

E-mail: fazilq.hasanov@socar.az


S.R.Rasulov, A.N.Zeynalov

Azerbaijan State Oil and Industry University, Baku, Azerbaijan

Increase of the efficiency of production of high viscous asphaltenic-paraffin oils


One of the most serious complications at production, transport and preparation of oil are asphalting pitch paraffin deposits. Their formations in the underground borehole equipment and also in discharge lines, pipelines of system of collecting increase costs of oil production. For the solution of these questions enough effective reagents aren't present.We have developed multicomponent and multipurpose MORE-R, RÇ-R reagents. Influence of these reagents on temperatures of hardening oils, dissertating of paraffin and its dissolution and also paraffin adjournment was investigated. New reagents took root at «Neft Dashlar» Square and satisfactory results are received. The offered three-parametrical Gershelya-Balkli model can be used for assessment of rheological oil parameters at their transportation.

Keywords: asphaltenic rubber paraffin sedimentation; pump–compression pipe; reagents; dispersion of paraffin; reology parametric.

One of the most serious complications at production, transport and preparation of oil are asphalting pitch paraffin deposits. Their formations in the underground borehole equipment and also in discharge lines, pipelines of system of collecting increase costs of oil production. For the solution of these questions enough effective reagents aren't present.We have developed multicomponent and multipurpose MORE-R, RÇ-R reagents. Influence of these reagents on temperatures of hardening oils, dissertating of paraffin and its dissolution and also paraffin adjournment was investigated. New reagents took root at «Neft Dashlar» Square and satisfactory results are received. The offered three-parametrical Gershelya-Balkli model can be used for assessment of rheological oil parameters at their transportation.

Keywords: asphaltenic rubber paraffin sedimentation; pump–compression pipe; reagents; dispersion of paraffin; reology parametric.

References

  1. A.V.Shariffulin, N.M.Nagimov, V.G.Kozin. Uglevodorodnye kompozity dlja udalenija asfal'tenosmoloparafinovyh otlozhenij //Geologija, geofizika i razrabotka neftjanyh i gazovyh mestorozhdenij. -2002.
    -№ 1. -C. 51-57.
  2. K.I.Matiyev, A.D.Aga-zade, S.S.Keldibayeva. Removal of asphaltene-resin-paraffin deposits of various fields //SOCAR Proceedings. -2016. –No. 4. -P. 64-68.
  3. A.N.Zeynalov. Study of chemical elements «MORE-R», «PG-R» efficiency against asphalt-paraffin deposits in oil field equipment //Proceedings of the Second International Scientific-Practical Conference «New Technologies in Oil & Gas Production». Baku: OilGasScientificResearchProject Institute, SOCAR, 6-7 september 2012. – P.177.
  4. R.M.Sattarov, A.N.Zeynalov. Improvement of efficiency and elimination of wax deposits in oil equipment //Azerbaijan Oil Industry. –2002. –No. 11. –P.53-57.
  5. Z.Wu, Z.Yang, L.Cao, G.Wang. Study on performance of surfactant-polymer system in deep reservoir //SOCAR Proceedings. -2016. -№ 1. -P.34-41.
  6. J.J.Wylde. Chemical treatments for paraffin evaluation and control //Oil & Gas Technology. – 2009. – No. 9. – P. 25-29.
  7. R . B a i l e y , L . H a m b e e k , J . R . S t e w a r t . N e w solution for paraffin Oil & Gas Technology. -2004. –No. 6. -P. 36-37.
  8. V.O.Nekuchaev, А.Y.Lyapin, M.M.Mikheev. Methods and results of static shear stress study of Timan-Pechora Province waxy crude oils using a controlled shear rate rheometer //SOCAR Proceedings. -2018. –No. 4. -P. 18-25.
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DOI: 10.5510/OGP20190100377

E-mail: rasulovsakit@gmail.com


V.F.Dyagilev, N.K.Lazutin, V.N.Baksheev

Industrial University of Tyumen, Branch in Nizhnevartovsk, Russia

Approbation of the assessing methodology for the impact nature of water injection on oil samples using the example of the North-Orekhovsky field


This paper deals with the existing oilfield separation systems of water injection in accordance with the directions of formation water selections. The studies found that the practical value of evaluation technique of pumping effect is: the determination of effective compensation of formation water selections by means of injection into production and injection wells; the definition of injection wells which are not working on displacement and production wells which are getting not enough download; supplementing for identifying the wells with inflow water; the determination of layers with movable remaining recoverable reserves; the evaluation of the proportion of remaining recoverable reserves which are made additionally by the adjacent production wells.

Keywords: oil recovery; water injection in the directions of selections; recovery zone; residual water; dehydration.

This paper deals with the existing oilfield separation systems of water injection in accordance with the directions of formation water selections. The studies found that the practical value of evaluation technique of pumping effect is: the determination of effective compensation of formation water selections by means of injection into production and injection wells; the definition of injection wells which are not working on displacement and production wells which are getting not enough download; supplementing for identifying the wells with inflow water; the determination of layers with movable remaining recoverable reserves; the evaluation of the proportion of remaining recoverable reserves which are made additionally by the adjacent production wells.

Keywords: oil recovery; water injection in the directions of selections; recovery zone; residual water; dehydration.

References

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  6. M.I.Maksimov. Geological basis of oil field development. M.: Nedra, 1975. 
  7. M.A.Tokarev. Integrated geological and industrial controls the current oil recovery in the displacement of oil by water. M.: Nedra, 1990.
  8. A.Kh.Mirzadjanzade, G.S.Stepanova. Mathematical theory in oil and gas production. M.: Nedra, 1977. 
  9. A.B.Kazhdan, O.I.Guskov. Mathematical methods in geology. M.: Nedra, 1990. 
  10. M.S.Arabadji, E.A.Bakirov, V.S.Melnychuk, R.V.Senyukov. Mathematical methods and computers in search and exploration. M.: Nedra, 1984. 
  11. L.F.Dementiev. Statistical methods of fieldgeological data processing and analysis. M.: Nedra, 1966.
  12. N.V.Smirnov, I.V.Dunin-Borkovskiy. Course of the probability theory and mathematical statistics. M.: Nauka, 1965.
  13. S.R.Rao. Linear statistical methods and their application. M.: Nauka, 1968.
  14. G.H.Gabitov, V.E.Andreev, R.M.Karimov. Multivariate statistical analysis for the optimization purpose of bottom-hole formation zone complex processing and prediction of their efficiency for the PU "Krasnokholmskneft" fields //Oilfield Engineering. -2005. –No. 4. –P. 34-40.
  15. Û.V.Zejgman, O.А.Gumerov, R.M.Karimov, G.А.Šamaev. Gidrodinamičeskie metody regulirovaniâ razrabotki neftânyh mestoroždenij //Materialy naučnopraktičeskoj konferencii «Аktual'nye voprosy razrabotki
    neftegazovyh mestoroždenij na pozdnih stadiâh. Tehnologii. Oborudovanie. Bezopasnost'. Èkologiâ». – Ufa: UGNTU, 2010.
  16. Analysis of the implementation of project indicators for 2012 and development of measures for the implementation of project solutions for 2013 for JSC «SN-MNG». Vol. 14. Scientific research reports.
    Nizhnevartovsk, 2013.
  17. N.K.Efimov. Tehnologii OVP v neftânyh skvažinah i puti povyšeniâ èffektivnosti RIR //Inženernaâ praktika. – 2011. – № 7. – S. 2-17.
  18. A.I.Khavkin. Physico-chemical technologies for lowpermeable layers enhanced oil recovery //Oil Industry. -1994. -№ 8. -P. 31-34.
  19. V.I.Levitsky, A.D.Mitrophanov. Isolation of watered intervals of productive formation AB4.5 Samotlor field viscoelastic systems. Tyumen: JSC SibINKOR, 1998.
  20. R.M.Karimov, V.F.Galiev, M.D.Idrisov. Аnaliz èffektivnosti vyrabotki zapasov učastka OOO SP «Vatojl» Vat'eganskogo mestoroždeniâ s ispol'zovaniem geologo-statističeskogo modelirovaniâ po priznakam geologičeskoj neodnorodnosti //Materialy I naučnopraktičeskoj konferencii «Problemy neftegazovogo kompleksa Zapadnoj Sibiri i puti povyšeniâ ego èffektivnosti». Kogalym: KogalymNIPIneft', 2001. Kn. II. – S. 184-188.
  21. A.V.Starkovsky. A n i n t e g r a t e d u s e o f p h y s i c a l - chemical impacttechnologies for the enhanced oil recovery // Oil Industry . – 2 0 1 1 . – N o . 5 . – P . 8 8 - 9 0 .
  22. R.А.Nugajbekov, А.V.Čibisov, R.M.Karimov. Perspektivnye napravleniâ dovyrabotki ostatočnyh zapasov Novo-Elhovskogo mestoroždeniâ //Sbornik naučnyh trudov «Metody uveličeniâ nefteotdača trudnoizvlekaemyh zapasov. Problemy i rešeniâ». Vypusk IV. Ufa: NIInefteotdača, 2003. –S. 86-92.
  23. S.M.Vainstock, N.Sh.Khayredinov, V.E.Andreev. Geological and technological features of the deposits development of the Kogalym region using of increasing oil recovery methods. Ufa: USPTU, 1999.
  24. R.M.Karimov. Principy operativnogo regulirovaniâ vyrabotki zapasov na raznyh stadiâh s ispol'zovaniem procedur regressionnogo analiza i kompleksnyh peremennyh //VI Rossijskij forum 24-27 oktâbrâ 2006 g. Materialy naučno-praktičeskaâ konferenciâ «Ènergoèffektivnost'. Problemy i rešeniâ». Ufa, 2006. –S. 35-36.
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DOI: 10.5510/OGP20190100378

E-mail: kpw72@yandex.ru


V.M.Shamilov, E.R.Babayev

Nanotechnology Department, SOCAR, Baku, Azerbaijan

Biocidal composition with copper nanoparticles for the oil industry


The proposed work presents the results of testing in the laboratory conditions of the developed multifunctional composition based on 30-50 nm copper nanoparticles and 1-butoxy-2-oxazolidinemethoxy propane as a biocidal composition and studying the possibility of its application in the oil industry. Sulfate-reducing bacteria were isolated from the reservoir waters of the Bibi-Heybat oil field on the Absheron Peninsula of Azerbaijan. The effectiveness of the prepared solution against biodegradation was studied in oil and cutting fluids. The antimicrobial efficacy of the investigated compound along with other components was studied by the disk diffusion method. The obtained data indicate that the proposed biocide composition quickly and effectively suppresses the growth of microorganisms. The latter fact is very important for the oil industry, since exactly sulfate-reducing bacteria are one of the main sources of biological corrosion and cause enormous damage every year.

Keywords: biocides; copper nanoparticles; 1-butoxy-2-oxazolidinemethoxy propane; sulfate-reducing bacteria.

The proposed work presents the results of testing in the laboratory conditions of the developed multifunctional composition based on 30-50 nm copper nanoparticles and 1-butoxy-2-oxazolidinemethoxy propane as a biocidal composition and studying the possibility of its application in the oil industry. Sulfate-reducing bacteria were isolated from the reservoir waters of the Bibi-Heybat oil field on the Absheron Peninsula of Azerbaijan. The effectiveness of the prepared solution against biodegradation was studied in oil and cutting fluids. The antimicrobial efficacy of the investigated compound along with other components was studied by the disk diffusion method. The obtained data indicate that the proposed biocide composition quickly and effectively suppresses the growth of microorganisms. The latter fact is very important for the oil industry, since exactly sulfate-reducing bacteria are one of the main sources of biological corrosion and cause enormous damage every year.

Keywords: biocides; copper nanoparticles; 1-butoxy-2-oxazolidinemethoxy propane; sulfate-reducing bacteria.

References

  1. R.Zh.Akhiyarov, Yu.G.Matveev, A.B.Laptev, D.E.Bugay. Saving technologies to prevent produced water infection by bacteria at oil enterprises //Oil and Gas Business. -2011. –No. 5. -P.232-242.
  2. D.D.Аndreeva, R.Z.Fahrutdinov. Korrozionnoopasnaâ mikroflora neftânyh mestoroždenij //Vestnik Kazanskogo Tehnologičeskogo Universiteta. -2013. -№10. -S.237-242.
  3. B.A.Suleimanov, F.S.Ismailov, E.F.Veliyev. Nanofluid for enhanced oil recovery //Journal of Petroleum Science and Engineering. –2011. –Vol.78. –Issue 2. –P.431–437.
  4. B.A.Suleimanov, E.F.Veliyev. The effect of particle size distribution and the nano-sized additives on the quality of annulus isolation in well cementing //SOCAR Proceedings. – 2016. - № 4. – C.4-10.
  5. Z.Wu, Z.Yang, L.Cao, G.Wang. Study on performance of surfactant-polymer system in deep reservoir //SOCAR Proceedings. –2016. -№1. –P.34-41.
  6. R.N.Bahtizin, R.M.Karimov, B.N.Mastobaev. The effect of high-molecular components on flow properties, depending on the structural-group and fractional oil content //SOCAR Proceedings. –2016. –No. 1. –P.42-50.
  7. V.M.Shamilov, E.R.Babayev, N.F.Alieva, F.V.Shamilov. Nanostructured biocidal composite for oil industry // Proceedings of the «Khazarneftgazyatag - 2016» scientificpractical conference. Baku, 2016. -P.119-124.
  8. A.A.Dmitrievskaya. Biocidal properties of metal nanoparticle suspensions and their oxides //Bulletin of Medical Internet Conferences. –2017. –Vol. 7. –No. 6. –P. 876-878.
  9. ASTM D4412-15. Standard test methods for sulfatereducing bacteria in water and water-formed deposits. ASTM International, West Conshohocken, PA, 2015, www. astm.org
  10. N.S.Hamidova, N.A.Azimov, A.V.Ahmedova. Corrosion protection of oil field system by «Oilgas» series’ reagents of complex action under conditions of watering and contamination by microorganisms //SOCAR Proceedings. - 2013. – No. 2. - P.71-75.
  11. Y.V.Andreeva, C.V.Ulahovich, A.R.Panteleeva, S.Yu.Egorov. The JSC «NAPOR» biocides influence on the sulphate reducing bacteria viability //Proceedings of Kazan University. Natural Sciences Series. –2007.
    –Vol. 149. –Issue 1. –P. 72-78.
  12. I.Bej. Biocidal compositions and methods of their application. RU Patent № 2515679, 2014.
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DOI: 10.5510/OGP20190100379

E-mail: valeh.shamilov@socar.az


A.D.Agazade, A.M.Samedov, M.E.Alsafarova, A.F.Akberova

«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan

Studies on the selection of effective demulsifiers for initial treatment of oil and dehydration of hardly breakable water-oil emulsion


Studies were conducted on the selection of effective demulsifiers for the initial preparation of water-oil emulsion and dehydration of a hard-to-break wateroil emulsion (TRVNE) formed during the preparation of crude oil. It has been established that, based on the results of a bootle test, the ND-12А demulsifier provides the maximum dehydration of oil in comparison with the dissolving agent Dissolvan-4411 under certain test conditions. As a result of tests with TRVNE samples, the ND-12А demulsifier was selected as an effective demulsifier. Unlike Dissolvan-4411, the demulsifier ND-12А makes it possible to completely destroy the TRVNE with a clear interface. The residual water content in the oil is minimal, and the mechanical impurities are in the order of the norm.

Keywords: water-oil emulsion; hard-to-break water-oil emulsion; demulsifier; bootle test; flow; demulsification conditions.

Studies were conducted on the selection of effective demulsifiers for the initial preparation of water-oil emulsion and dehydration of a hard-to-break wateroil emulsion (TRVNE) formed during the preparation of crude oil. It has been established that, based on the results of a bootle test, the ND-12А demulsifier provides the maximum dehydration of oil in comparison with the dissolving agent Dissolvan-4411 under certain test conditions. As a result of tests with TRVNE samples, the ND-12А demulsifier was selected as an effective demulsifier. Unlike Dissolvan-4411, the demulsifier ND-12А makes it possible to completely destroy the TRVNE with a clear interface. The residual water content in the oil is minimal, and the mechanical impurities are in the order of the norm.

Keywords: water-oil emulsion; hard-to-break water-oil emulsion; demulsifier; bootle test; flow; demulsification conditions.

References

  1. Yu.G.Frolov. Course in colloid chemistry. Surface occurrences and disperse systems. M.: Khimiya, 1982.
  2. G.N.Pozdnyshev. Stabilization and breakdown of oil emulsions. M.: Nedra, 1982.
  3. K.I.Matiyev, A.D.Aga-zade, S.S.Keldibayeva. Removal
    of asphaltene-resin-paraffin deposits of various fields // SOCAR Proceedings. -2016. –No. 4. -P.64-68.
  4. R.N.Bahtizin, R.M.Karimov, B.N.Mastobaev. The effect of high-molecular components on flow properties, depending on the structural-group and fractional oil content //SOCAR Proceedings. -2016. –No.1. -P.42-50.
  5. E.K.Tolepbergenov. New approach for refining of oil pit on "Uzen" and "Karamandybas" fields //SOCAR Proceedings. -2012. -No.4. -P.43-52.
  6. L.P.Semihina, F.G.Šabarov, А.G.Perekupka. Razrabotka neftepromyslovyh reagentov na osnove židkokristalličeskoj nanotehnologii //Sbornik trudov regional'noj naučnopraktičeskoj konferencii «Nanotehnologii Tûmenskoj oblasti». Tûmen': Izd-vo TûmGU, 2009.
  7. L.P.Semikhina, A.G.Perekupka, D.V.Plotnikova, D.V.Zhuravskiy. Demulsifiers effectiveness increase due to their nano-modifications production //Tyumen State University Herald. Physical and Mathematical Modeling. Oil, Gas, Energy. -2009. -No. 6. -P. 88-93.
  8. А.Sejdov, F.Pronin, А.Âgudin. Аnaliz rynka neftepromyslovyh reagentov. M.: АT Konsalting kompanii, 2008.
  9. L.P.Semikhina. Method of determination of dielectric and dynamic magnetic conductivity of substances in lowfrequency field by means of inductive L-cells. RU Patent No. 2347230, 2009.
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DOI: 10.5510/OGP20190100380

E-mail: aygunshukurova@gmail.com


S.V.Kitaev1, I.R.Baikov1, O.V.Smorodova1, V.I.Semin2

1Ufa State Petroleum Technological University, Ufa, Russia; 2LLC «Burovaya tekhnika Scientific and Production Association», Moscow, Russia

Interpretation of bearings vibrations vibrospects of gas-pumping units by self-organizing systems methods


The article is devoted to the development of special methods for forecasting accidents of gas-pumping unites (GPU) based on the interpretation of the vibrational spectra of the oscillations of the low-pressure turbine thrust bearing housing (PMO TND)  body case. When developing a complex defect, it is proposed to use the value of the correlation dimension, determined on the basis of the one-dimensional frequency range of the measured vibration velocity of the housing of the GUP TND GPA, as an additional criterion. It is shown that in the defect-free state of the gas pumping unit, the dependence of the correlation dimension of the strange attractor (v) on the dimension of the enclosed space (m) has the form of a curve with saturation and in the corresponding coordinates goes to the asymptotic horizontal boundary. If there is a danger of an emergency failure, then the saturation of the function v(m) is not observed in the entire research area, the correlation dimension v(m) increases monotonically with the enclosed space increasing dimension.

Keywords: vibrospectrum; amplitude; correlation dimension; attractor; phase space; deterministic chaos.

The article is devoted to the development of special methods for forecasting accidents of gas-pumping unites (GPU) based on the interpretation of the vibrational spectra of the oscillations of the low-pressure turbine thrust bearing housing (PMO TND)  body case. When developing a complex defect, it is proposed to use the value of the correlation dimension, determined on the basis of the one-dimensional frequency range of the measured vibration velocity of the housing of the GUP TND GPA, as an additional criterion. It is shown that in the defect-free state of the gas pumping unit, the dependence of the correlation dimension of the strange attractor (v) on the dimension of the enclosed space (m) has the form of a curve with saturation and in the corresponding coordinates goes to the asymptotic horizontal boundary. If there is a danger of an emergency failure, then the saturation of the function v(m) is not observed in the entire research area, the correlation dimension v(m) increases monotonically with the enclosed space increasing dimension.

Keywords: vibrospectrum; amplitude; correlation dimension; attractor; phase space; deterministic chaos.

References

  1. R.N.Bakhtizin, F.M.Mustafin, L.I.Bykov, et al. Construction and operation of pipelines. Innovations and priorities //SOCAR Proceedings. –2016. –No. 3. –P.52-58.
  2. K.K.Argunova, E.A.Bondarev, I.I.Rozhin. Analytical equations of the state of natural gases and their role in mathematical modeling //SOCAR Proceedings. –2016. –No.4. –P.41-48.
  3. V.I.Kucheryavy, V.L.Savich, S.N.Milkov. Evaluation of the reliability of the underground oil and gas pipeline on stability criterion //SOCAR Proceedings. –2018. –No.4. –P.59-64.
  4. O.A.Dyshin. Wavelet solving method of nonstasionary liquid filtration problem in crack-porosity of circular form //SOCAR Proceedings. –2016. –No.1. –P.67-79.
  5. A.Kh.Mirzadjanzade, Ch.A.Sultanov. Diacoptics of oil recovery processes. Baku: Azerbaijan, 1995.
  6. I.R.Baykov, O.V.Smorodova. Diagnosis of the technical condition of the technological equipment of gas pipelines //Gas industry. -1998. –No.6. -P.15-17.
  7. G.Nikolis, I.Prigozhin. Cognition of the complex. M.: Mir, 1990.
  8. I.R.Baykov, T.G.Zhdanova, E.A.Gareyev. Modeling of technological processes of pipeline transport of oil and gas. Ufa: UNI, 1994.
  9. A.Kh.Mirzadjanzade, M.M.Hasanov, R.N.Bahtizin. Study about simulation of complicated systems in oil & gas recovery. Nonlinearity, Nonequilibrium, Uncertainty. Ufa.: Gilem, 1999.
  10. Yu.I.Neymark, P.S.Landa. Stochastic and chaotic oscillations. M.: Nauka, 1987.
  11. I.R.Baykov, O.V.Smorodova, E.A.Gareyev, F.M.Aminev. Methods of the theory of self-organization for diagnosing GPA problems //Gas industry. -1999. –No.8. -P.25-28.
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DOI: 10.5510/OGP20190100381

E-mail: svkitaev@mail.ru


T.F.Akramov, N.R.Yarkeeva

Ufa State Petroleum Technological University, Ufa, Russia

Rational usage of associated petroleum gas


In article is considered the problem of associated petroleum gas (APG) combustion in the oil companies based in Russia. At the moment, the utilization percent of the gas extracted together with petroleum, does not reach does not reach necessary indicators normalized by the legislation. According to official data no more than 80% of produced APG are rationally utilized (a rated value – 95%). Due to combustion of APG is followed by an oxygen consumption and an excessive heat generation it negatively affects on the environment and as a result leads to enhanced greenhouse effect. In article is set a task to reveal main directions of associated petroleum gas utilization and to determine possible efficiency of applied technologies on the example fields of the oil and gas production department Yamashneft. During the research most common methods of APG usage within industrial base were studied.

Keywords: associated petroleum gas; torch; thermal furnaces PPNT-1,6; gas-piston installations AGP-200; gas turbine installations CAPSTONE C-class; water-gas mixture.

In article is considered the problem of associated petroleum gas (APG) combustion in the oil companies based in Russia. At the moment, the utilization percent of the gas extracted together with petroleum, does not reach does not reach necessary indicators normalized by the legislation. According to official data no more than 80% of produced APG are rationally utilized (a rated value – 95%). Due to combustion of APG is followed by an oxygen consumption and an excessive heat generation it negatively affects on the environment and as a result leads to enhanced greenhouse effect. In article is set a task to reveal main directions of associated petroleum gas utilization and to determine possible efficiency of applied technologies on the example fields of the oil and gas production department Yamashneft. During the research most common methods of APG usage within industrial base were studied.

Keywords: associated petroleum gas; torch; thermal furnaces PPNT-1,6; gas-piston installations AGP-200; gas turbine installations CAPSTONE C-class; water-gas mixture.

References

  1. А.Û.Knižnikov, V.V.Tetel'min, Û.P.Bunina. Аnalitičeskij doklad po probleme racional'nogo ispol'zovaniâ poputnogo neftânogo gaza. M.: WWF Rossii, 2015. –C. 44.
  2. Û.V.Zejgman, G.А.Šamaev. Spravočnik neftânika //Sbor i podgotovka produkcii skvažin. Ufa: TАU, 2005.
  3. P.А.Kirûšin. Poputnyj neftânoj gaz v Rossii: «Sžigat' nel'zâ, pererabatyvat'!» //Аnalitičeskij doklad ob èkonomičeskih i èkologičeskih izderžkah sžiganiâ poputnogo neftânogo gaza v Rossii. M.: Vsemirnyj fond dikoj prirody (WWF), 2013. —C. 88.
  4. А.А.Gajle, А.I.Bogomolov, V.V.Gromova. Himiâ nefti i gaza. Učebnoe posobie dlâ vuzov. M.: Himiâ, 2005.
  5. V.А.Аmiân, N.P.Vasil'eva. Dobyča gaza. M.: Nedra, 1974.
  6. A.Bahadori. Liquefied petroleum gas (LPG) recovery //The Journal of Natural Gas Processing. –2014. –Vol. 600. –P.547-590.
  7. A.A.Solovyanov. Associated petroleum gas flaring and environment //Environment Protection in Oil and Gas Complex. -2012. –No. 6. –P. 21- 27.
  8. Sh.Jafarinejad. Introduction to the Petroleum Industry //The Journal of Petroleum Waste Treatment and Pollution Control. –2017. –Vol. 42. -P. 1-17.
  9. S.O.Vuk Rajović, F.Kiss, N.Maravić, O.Bera. Environmental flows and life cycle assessment of associated petroleum gas utilization via combined heat and power plants and heat boilers at oil fields //The Journal of Energy Conversion and Management. – 2016. –Vol.118. –P.96-104.
  10. Postanovlenie Pravitel'stva RF ot 08/11/2012 N 1148 «Ob osobennostâh isčisleniâ platy za negativnoe vozdejstvie na okružaûŝuû sredu pri vybrosah v atmosfernyj vozduh zagrâznâûŝih veŝestv, obrazuûŝihsâ
    pri sžiganii na fakel'nyh ustanovkah i (ili) rasseivanii poputnogo neftânogo gaza».
  11. I.R.Baikov, O.V.Smorodova. The perspectives of energy saving at production fields objects usage // Transport and Storage of Oil Products and Hydrocarbons. –2009. –No.6. –P.10-12.
  12. S.V.Kitaev, E.А.Kolokolova, O.V.Smorodova. Utilizaciâ poputnogo neftânogo gaza na ustanovkah sžiganiâ promstokov //Materialy IV Meždunarodnoj učebnoj naučno-praktičeskoj konferencii «Truboprovodnyj
    transport». Ufa, 2008.
  13. S.O.H.Hassani, E.S.Silva, A.M.Al Kaabi. The role of innovation and technology in sustaining the petroleum and petrochemical industry //The Journal of Technological Forecasting and Social Change. –2017. –Vol. 119. –P. 1-17.
  14. R.S.Gil'mutdinov, Û.V.Аntipin, N.R.Ârkeeva. Processy, privodâŝie k vydeleniû serovodoroda i obrazovaniû otloženij sul'fida železa v skvažinah na pozdnej stadii razrabotki // Materialy IV kongressa neftegazopromyšlennikov Rossii. Ufa, 2003.
  15. S.O.M.Terhan, K.Comakli. Energy and exergy analyses of natural gas-fired boilers in a district heating system //The Journal of Applied Thermal Engineering. –2017. –Vol.121. –P. 380-387.
  16. X.Zhu, X.Sui, Y.Zhao, et al. Experimental study of the flow and heat transfer of a gas–water mixture through a packed channel //The Journal of Science Bulletin. – 2016. –Vol.61. –P.406-415.
  17. M.D.Valeev, R.M.Akhmetzyanov, D.V.Shamenin, M.A.Bagautdinov. Pumping plant for gas withdrawal from annular space in oil well. RU Patent No. 2630490, 2017.
  18. V.I.Krûčkov, V.E.Peškov, Û.А.Ŝemelinin. Sposob vytesneniâ nefti iz plasta. Patent RF № 1810505, 1991.
  19. L.Raslavičius, A.Keršys, S.Mockus, et al. Liquefied petroleum gas (LPG) as a medium-term option in the transition to sustainable fuels and transport //The Journal of Renewable and Sustainable Energy Reviews. –2014. – Vol. 32. –P.513-525.
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DOI: 10.5510/OGP20190100382

E-mail: akramov.timur@yandex.ru