SOCAR Proceedings

SOCAR Proceedings

Published by "OilGasScientificResearchProject" Institute of State Oil Company of Azerbaijan Republic (SOCAR).

SOCAR Proceedings is published from 1930 and is intended for oil and gas industry specialists, post-graduate (students) and scientific workers.

Journal is indexed in Web of Science (Emerging Sources Citation Index), SCOPUS and Russian Scientific Citation Index, and abstracted in EI’s Compendex, Petroleum Abstracts (Tulsa), Inspec, Chemical Abstracts database.

A. R. Karimov1,2,3, V. K. Bogdanov1, R. A. Valiullin4, R. F. Sharafutdinov4, A. Sh. Ramazanov4, F. I. Ibadov5

1MEPhI, Moscow, Russia; 2Institute for High Temperatures, RAS, Moscow, Russia; 3PRUE G.V. Plekhanov, Moscow, Russia; 4Bashkir State University, Ufa, Russia; 5SOCAR, Baku, Azerbaijan

Usage of internal airlift for exploration of oil deposits


The paper looks at the processes in an oil dispersed medium with dissolved gas. The model of interaction for the growing bubbles with acoustic fields is presented. It is shown how the change in pressure and oil saturation (namely, the density of oil particles in the entire flow) of the medium is associated with temperature fields in the system. Proceeding from this point, at a qualitative level, thermograms of wells obtained in the process of oil production is analyzing.

Keywords: colloidal system; dispersed bubbles; oil; heat of oil degassing; thermal fields.

The paper looks at the processes in an oil dispersed medium with dissolved gas. The model of interaction for the growing bubbles with acoustic fields is presented. It is shown how the change in pressure and oil saturation (namely, the density of oil particles in the entire flow) of the medium is associated with temperature fields in the system. Proceeding from this point, at a qualitative level, thermograms of wells obtained in the process of oil production is analyzing.

Keywords: colloidal system; dispersed bubbles; oil; heat of oil degassing; thermal fields.

References

  1. Matar, S., Hatch, L. F. (2001). Chemistry of petrochemical processes. Elsevier, Gulf Professional Publishing.
  2. Speight, J. G. (2017). Lange’s handbook of chemistry. McGraw-Hill Education.
  3. Simanzhenkov, V., Idem, R. (2003). Crude oil chemistry. New York: Marcel Dekker.
  4. Kelbaliev, G. I., Rasulov, S. R., Tagiev, D. B., Mustafayeva, G. R. (2017). Mechanics and rheology of oil dispersed systems. Moscow: Mask
  5. Abramov, V. O., Abramova, A. V., Bayazitov, V. M., et al. (2017). Acoustic and sonochemical methods for altering the viscosity of oil during recovery and pipeline transportation. Ultrasonics Sonochemistry, 35A, 389-396.
  6. Mohammadian, E., Junin, R., Rahmani, O., KamalIdris, A. (2013). Effects of sonication radiation on oil recovery by ultrasonic waves stimulated water-flooding. Ultrasonics, 53, 607.
  7. Gbadamosi, A. O., Junin, R., Manan, M. A., et al. (2019). An overview of chemical enhanced oil recovery: recent advances and prospects. International Nano Letters, 9, 171-202.
  8. Suslick, K. S., Didenko, Y., Fang, M. M., et al. (1999). Acoustic cavitation and its chemical consequences. Philosophical Transactions of the Royal Society A, 357, 335-353.
  9. Karimov, A. R., Bogdanov, V. K., Valiullin, R. A., et al. (2021). Acoustic field induced processes of structure formation in high-molecular media. Advances in Applied Physics, 9, 2, 128
  10. Suslick, K. S., Flannigan, D. J. (2008). Inside a collapsing bubble: sonoluminescence and the conditions during cavitation. Annual Review of Physical Chemistry, 59, 659-683.
  11. Caruso, M. M., Davis, D. A., Shen, Q., et al. (2009). Mechanically induced chemical changes in polymeric materials. Chemical Reviews, 109, 5755-5798.
  12. Valiullin, R. A., Sharafutdinov, R. F., Ramazanov, A. Sh. (2004). A research into thermal field in fluid-saturated porous media. Powder Technology, 148, 72-77.
  13. Akartuna, I., Studart, A. R., Tervoort, E. (2008). Stabilization of oil-in-water emulsions by colloidal particles modified with short amphiphiles. Langmuir, 24, 7161-7168.
  14. Varaksin, A. Y. (2013). Fluid dynamics and thermal physics of two-phase flows: Problems and achievements. High Temperatures, 51, 377–407.
  15. Xiaoyan, L., Zhonghua, W., Lijun, L., et al. (2014). Experimental study on characteristics of oil particle distribution in water-gelled crude oil two-phase flow system. Advances in Mechanical Engineering, 6.
  16. Ding, B., He, L. P., Luo, J. H., et al. (2016). Determination of particle size of heavy oil in water dispersion system by ultrasonic attenuation method. Journal of Petroleum Science and Engineering, 146, 764–769.
  17. Berger, K. J., Hrenya, C. M. (2014). Challenges of DEM: II. Wide particle size distributions. Powder Technology, 264, 627–633.
  18. Temperley, H. N. V., Rawlinson, J. S., Rushbrook, G. S. (1968). Physics of simple liquids. North-Holand Publishing Company.
  19. Conway, J. H., Sloane, N. J. (1999). A sphere packings, lattices and groups. Springer-Verlag.
  20. Jahne, B., Haußecker, H. (1998). Air-water gas exchange. Annual Review of Fluid Mechanics, 30, 443–468.
  21. Babaeva, N. Yu, Berry, R. S., Naidis, G. V., et al. (2016). Kinetic and electrical phenomena in gas-liquid systems. High Temperatures, 54, 745-766.
  22. Gimatudinov, Sh. K., Shirkovsky, A. I. (1982). Physics of oil and gas reservoir. Moscow: Nedra.
  23. Levich, V. G. (1977). Physicochemical hydrodynamics. New York: Prentice-Hall, Englewood Cliffs.
  24. Soto, Á. M., Prosperetti, A., Lohse, D., et al. (2017). Gas depletion through single gas bubble diffusive growth and its effect on subsequent bubbles. Journal of Fluid Mechanics, 83, 474-490.
  25. Karimov, A., Bogdanov, V., Valiullin, R., et. al. (2022). The degassing processes for oil media in acoustic fields and their applications. Polymers, 14, 1497.
  26. Galyamina, I. P. (1978). Little encyclopedia. Moscow: Soviet Encyclopedia.
  27. Boldev, R., Palanichamy, P., Rajendran, V. (2004). Science and technology of ultrasonics. Pangbourne, U.K.: Alpha Science International
  28. Valiullin, R. A., Ramazanov, Sh., Sharafutdinov, R. F. (1998). Thermometry of reservoirs with multiphase flows. Ufa: Publishing house Bashkir.
  29. Valiullin, A., Ramazanov, A. Sh., Sharafutdinov, R. F. (1994). Barothermal effect in three-phase filtration with phase transitions. Fluid Dynamics, 29, 834-837.
  30. Karimov, A. R., Taleisnik, M. A., Savenkova, T. V., et al. (2019). The influence of velocity field on simple chemical reactions in viscous flow. Physica Scripta, 94(4), 045002.
  31. Gil’manov, A. Y., Fedorov, K. M., Shevelev, A. P. (2020). Integral model of steam-assisted gravity drainage. Fluid Dynamics, 55, 793–803.
  32. Kireev, V. N., Nizamova, A. D., Urmancheev, S. F. (2019). Some features of hydrodynamic instability of a plane channel flow of a thermoviscous fluid. Fluid Dynamics, 54, 978–982.
  33. Valiuillin, R. A., Sharafutdinov, R. F., Ramazanov, A. Sh., et al. (2021). Method for assessing oil reservoir saturation characteristics, RU Patent 2754138.
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DOI: 10.5510/OGP20220300702

E-mail: arkarimov@mephi.ru


A. S. Hasanov

«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan

About reflection deep fault as a result of geophysical (2D seismic and high precision gravimetric) study (on the example of the West Caspian deep fault)


Since the beginning of the last century, geological and geophysical studies have been carried out in large volumes on the territory of Azerbaijan in order to study the oil and gas content, study the sources of earthquakes and other geological issues and compile sections, maps, reports, etc. In recent years, work has been carried out to clarify and re-evaluate the studies carried out with the use of new equipment. From this point of view, the issue on the agenda was the extent to which the identified deep faults in the oil and gas regions of Azerbaijan are accurate. In this article, the results of new geophysical (2D seismic and high-precision gravimetric) data obtained in the area passing through the West Caspian deep fault were considered, and it was found that the fracture did not find its reflection.

Keywords: deep fault; geosynclines; gravimetric exploration; seismic exploration; gravity; sediments; anomalies; gradient.

Since the beginning of the last century, geological and geophysical studies have been carried out in large volumes on the territory of Azerbaijan in order to study the oil and gas content, study the sources of earthquakes and other geological issues and compile sections, maps, reports, etc. In recent years, work has been carried out to clarify and re-evaluate the studies carried out with the use of new equipment. From this point of view, the issue on the agenda was the extent to which the identified deep faults in the oil and gas regions of Azerbaijan are accurate. In this article, the results of new geophysical (2D seismic and high-precision gravimetric) data obtained in the area passing through the West Caspian deep fault were considered, and it was found that the fracture did not find its reflection.

Keywords: deep fault; geosynclines; gravimetric exploration; seismic exploration; gravity; sediments; anomalies; gradient.

References

  1. Babayev, D. KH., Gadzhiyev, A. N. (2006). Glubinnoye stroyeniye i perspektivy neftegazonosnosti basseyna Kaspiyskogo morya. Baku: Nafta-press.
  2. Grushinsky, N. P., Sazhina, N. B. (1972). Gravity exploration. Moscow: Nedra.
  3. Antonov, Yu. V., Zhavoronki, V. I., Slyusarev, S. V. (1999). New possibilities of gravimetry in the study of the Earth's crust geological. Geophysics, 3, 47-52
  4. Lingshin, M., Rui, G., Ye, G. (1988). Research of the gravity field in the northern border zone of the Qinghai-Tibet Plateau. Geophysical and Geochemical Exploration, 22(3), 183-190.
  5. Alekseyev, V. V., Gadzhiyev, T. G., Karkoshkin, A. I., Khesin, B. E. (1988). Gravimagnitnyye anomalii Azerbaydzhana i ikh geologicheskoye istolkovaniye. Ob"yasnitel'naya zapiska k «Karte gravimagnitnykh anomaliy Azerbaydzhanskoy SSR». Leningrad.
  6. Mamedov, S., G., Gasanov, A. S. (1996). Technique of determination of damage zone by mud volcanos gravimetric prospecting data. In: Oil and Gas Processing and Petrochemistry of the Caspian Sea Conference and Exhibition. Baku: SOCAR.
  7. Yusubov, N. P. (2017). To the issue of presence of West Caspian fault. Azerbaijan Oil Industry, 4, 10-17.
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DOI: 10.5510/OGP20220300703

E-mail: alladdin.hasanov@socar.az


M. E. Loginova1, G. V. Konesev1, G. A. Teptereva1, E. V. Movsumzade1, E. M. Babushkin2, М. G. Buyanova1

1Ufa State Petroleum Technical University, Ufa, Russia; 2Industrial University of Tyumen, Tyumen, Russia

Justification of the formulation of modified drilling mud for the construction of the transport part of wells with a horizontal termination in the fields of the north of Western Siberia


The article considers the rationale for the formulation of an inhibitory clay-free drilling mud, including a complex reagent Polysil Potassium and CLSP for the conditions of deposits in the regions of Western Siberia. By the method of the planned experiment, the main equations of the main indicators (factors) of the studied drilling mud are obtained. According to the obtained dependencies, the concentrations of these reagents are selected, taking into account the specified parameters (FL = (up to 6) ml3/30 min, PV = (10-30) sP, YP = (80-150) dPa). In this paper, the results of regression analysis are carried out, with the help of which the dependences of the influence of the concentrations of the Polysil Potassium composition and pitch carbolignosulfonate on the properties of a clay-free water-based drilling mud are constructed. The regression analysis of drilling mud formulations has established that in order to maintain optimal technological parameters of sludge transport during drilling in the temperature range from 25 to 160 °C, the optimal ones are: the content of Polysil Potassium is 2.5%, CLSP is not more than 3%. This optimized system has a low dispersing capacity and satisfactory filtration and rheological characteristics.

Keywords: composition optimization; regression equation; inhibiting drilling fluids; complex reagents.

The article considers the rationale for the formulation of an inhibitory clay-free drilling mud, including a complex reagent Polysil Potassium and CLSP for the conditions of deposits in the regions of Western Siberia. By the method of the planned experiment, the main equations of the main indicators (factors) of the studied drilling mud are obtained. According to the obtained dependencies, the concentrations of these reagents are selected, taking into account the specified parameters (FL = (up to 6) ml3/30 min, PV = (10-30) sP, YP = (80-150) dPa). In this paper, the results of regression analysis are carried out, with the help of which the dependences of the influence of the concentrations of the Polysil Potassium composition and pitch carbolignosulfonate on the properties of a clay-free water-based drilling mud are constructed. The regression analysis of drilling mud formulations has established that in order to maintain optimal technological parameters of sludge transport during drilling in the temperature range from 25 to 160 °C, the optimal ones are: the content of Polysil Potassium is 2.5%, CLSP is not more than 3%. This optimized system has a low dispersing capacity and satisfactory filtration and rheological characteristics.

Keywords: composition optimization; regression equation; inhibiting drilling fluids; complex reagents.

References

  1. (2018). Proceedings of the XVIII conference of young scientists and specialists of the Branch of LLC «LUKOILEngineering ««KogalymNIPIneft» in Tyumen. Tyumen: Tyumen Press House.
  2. Tiab, J., Donaldson, E. Ch. (2009). Petrophysics: theory and practice. - studies of reservoir properties of rocks and the movement of reservoir fluids. Moscow: Premium Engineering LLC.
  3. Osipov, V. I., Sokolov, V. N. (2013). Clays and their properties. Composition, structure and formation of properties. Moscow: GEOS.
  4. Konesev, G. V., Agliullin, A. H., Loginova, M. E., et al. (2020). Application of the NMR relaxometry method for evaluating the inhibitory properties of water-based drilling fluids. Problems of Collecting, Preparing and Transporting Oil and Petroleum Products, 3(125), 20-28.
  5. Babushkin, E. V., Buyanova, M. G., Konesev, G. V., et al. (2018). Development of inhibiting drilling fluids to improve the efficiency of well construction in difficult mining and geological conditions. Nanotechnologies in Construction, 10(2), 42-62.
  6. Buyanova, M. G., Babushkin, E. V., Agliullin, A. H., Konesev, G. V. (2018). Analysis of the use of inhibiting drilling mud to improve the efficiency of the construction of shallow wells in difficult mining and geological conditions. Construction of Oil and Gas Wells on Land and at Sea, 10, 29-32.
  7. Buyanova, M. G., Babushkin, E. V., Konesev, G. V., et al. (2020). The use of inhibiting drilling mud in the construction of horizontal wells of a three-column structure. Oilfield Engineering, 10(622), 12-16.
  8. Gaidadin, A. N., Efremova, S. A. (2008). Application of the full factorial experiment during the research: methodical instructions. Volgograd: VolGTU.
  9. Nalimov, V. V., Chernova, N. A. (1965). Statistical methods of planning experiments. Moscow: Nauka.
  10. Spirin, N. A., Lavrov, V. V., Zainullin, L. A., et al. (2015). Methods of planning and processing the results of an engineering experiment. Yekaterinburg: LLC «UINC».
  11. Khrisanov, N. N. (2016). Planning of the experiment: methodical instructions. Samara: SSTU.
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DOI: 10.5510/OGP20220300704

E-mail: ufamel@yandex.ru


B. A. Suleimanov, H. F. Abbasov

«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan

Enhanced oil recovery mechanism with nanofluid injection


The development and application of enhanced oil recovery technologies using nanofluids have been observed in last decade. It was found that the use of these reagents leads to the wettability alteration of the pore walls of the rock, an interfacial tension reduction, a decrease in oil viscosity, and an increase in the disjoining pressure. This paper presents the results of studying the displacement of residual oil on homogeneous quartz sandstone using the nanofluids, obtained by peptizing the sediments in a mixture of seawater with calcium and magnesium salts. Nitric and organic acids were used as peptizing agents. When using the developed nanofluids, an increase in oil production by 15-20% was achieved in comparison with seawater. A new approach for the mechanism of action of nanoparticles on the formation, leading to an increase in oil production, is proposed.

Keywords: oil recovery; displacement efficiency; nanofluid; peptization; wettability alteration; interfacial tension.

The development and application of enhanced oil recovery technologies using nanofluids have been observed in last decade. It was found that the use of these reagents leads to the wettability alteration of the pore walls of the rock, an interfacial tension reduction, a decrease in oil viscosity, and an increase in the disjoining pressure. This paper presents the results of studying the displacement of residual oil on homogeneous quartz sandstone using the nanofluids, obtained by peptizing the sediments in a mixture of seawater with calcium and magnesium salts. Nitric and organic acids were used as peptizing agents. When using the developed nanofluids, an increase in oil production by 15-20% was achieved in comparison with seawater. A new approach for the mechanism of action of nanoparticles on the formation, leading to an increase in oil production, is proposed.

Keywords: oil recovery; displacement efficiency; nanofluid; peptization; wettability alteration; interfacial tension.

References

  1. Zhang, P., Tweheyo, M. T., Austad, T. (2007). Wettability alteration and improved oil recovery by spontaneous imbibition of seawater into chalk: Impact of the potential determining ions Ca2+, Mg2+, and SO42-. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 301, 199.208.
  2. Fathi, S. J., Austad, T., Strand, S. (2010). Wettability alteration in carbonates: the effect of water-soluble carboxylic acids in crude oil. Energy & Fuels, 24, 2514.2519.
  3. Fathi, S. J., Austad, T., Strand, S. (2011, April). Improved oil recovery in carbonates by modified seawater - Optimal ionic composition and salinity. In: 16th European Symposium on Improved Oil Recovery, Cambridge, U.K.
  4. Suleimanov, B. A., Latifov, Y. A., Veliyev, E. F., Frampton, H. (2018). Comparative analysis of the EOR mechanisms by using low salinity and low hardness alkaline water. Journal of Petroleum Science and Engineering, 162, 35-43.
  5. Zhang, P., Tweheyo, M. T., Austad, T. (2007). Wettability alteration and improved oil recovery by spontaneous imbibition of seawater into chalk: Impact of the potential determining ions Ca2+, Mg2+, and SO42-. Journal of Petroleum Science and Engineering, 301, 199.208.
  6. Tang, G. Q., Morrow, N. R. (1999). Influence of brine composition and fines migration on crude oil/brine/rock interactions and oil recovery. Journal of Petroleum Science and Engineering, 24(2.4), 1.6.
  7. Lager, A., Webb, K., Black, C., et al. (2008). Low salinity oil recovery - An experimental investigation. SPWLA-2008-v49n1a2. Petrophysics, 49(01).
  8. Ligthelm, D. J., Gronsveld, J., Hofman, J., et al. (2009, June). Novel waterflooding strategy by manipulation of injection brine composition. SPE-119835-MS. In: EUROPEC/EAGE Conference and Exhibition. Society of Petroleum Engineers.
  9. Austad, T., Rezaeidoust, A., Puntervold, T. (2010, April). Chemical mechanism of low salinitywater flooding in sandstone reservoirs. SPE-129767-MS. In: SPE Improved Oil Recovery Symposium. Society of Petroleum Engineers.
  10. Suleimanov, B. A, Abbasov, H. F. (2017). Chemical control of quartz suspensions aggregative stability, Journal of Dispersion Science and Technology, 38(8), 1103-1109.
  11. Masimov, E. A., Abbasov, H. F. (2012). Refractometry determination of the hydration number of ions in diluted aqueous solutions of magnesium sulfate. Russian Journal of Physical Chemistry A, 86(3), 399.401.
  12. Abbasov, H. F. (2022). A new model for the relative viscosity of aqueous electrolyte solutions. Chemical Physics Letters, 800, 139670.
  13. Debnath, A., Pandey, A., Chaturvedi, K. R., Sharma, T. (2022). Evaluation of performance spectra of mono and divalent low saline brine injection in sandy-carbonates for mobilization of crude oil. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 640, 128506.
  14. Torsater, O. (2021). Application of nanoparticles for oil recovery. Nanomaterials (Basel), 11(5), 1063.
  15. Ju, B., Fan, T., Ma, M. (2006). Enhanced oil recovery by flooding with hydrophilic nanoparticles. China Particuology, 4(1), 41-46.
  16. Onyekonwu, M., Ogolo, N. A. (2010, July). Investigating the use of nanoparticles in enhancing oil recovery. SPE-140744-MS. In: Nigeria Annual International Conference and Exhibition. Society of Petroleum Engineers.
  17. Sun, X., Zhang, Y., Chen, G., Gai, Z. (2017). Application of nanoparticles in enhanced oil recovery: a critical review of recent progress. Energies, 10(3), 345.
  18. Khalil, M., Jan, B. M., Tong, C. W., Berawi, M. A. (2017). Advanced nanomaterials in oil and gas industry: Design, application and challenges. Applied Energy, 191, 287.310.
  19. Kazemzadeh, Y., Shojaei, S., Riazi, M., Sharifi, M. (2019). Review on application of nanoparticles for EOR purposes: A critical review of the opportunities and challenges. Chinese Journal of Chemical Engineering, 27(2), 237-246.
  20. Agi, A., Junin, R., Gbadamosi, A. (2018). Mechanism governing nanoparticle flow behaviour in porous media: insight for enhanced oil recovery applications. International Nano Letters, 8, 49.77.
  21. Suleimanov, B. A., Ismailov, F. S., Veliyev, E. F. (2011). Nanofluid for enhanced oil recovery. Journal of Petroleum Science and Engineering, 78(2), 431-437.
  22. Hendraningrat, L., Li, S., Torsater, O. (2013). A coreflood investigation of nanofluid enhanced oil recovery. Journal of Petroleum Science and Engineering, 111, 128-138.
  23. Hadia, N. J., Ng, Y. H., Stubbs, L. P., Torsater, O. (2021). High salinity and high temperature stable colloidal silica nanoparticles with wettability alteration ability for EOR Applications. Nanomaterials, 11(3), 707.
  24. Li, S., Torsater, O. (2015, October). The impact of nanoparticles adsorption and transport on wettability alteration of water wet Berea sandstone. SPE-176256-MS. In: SPE/IATMI Asia Pacific Oil & Gas Conference and Exhibition. Society of Petroleum Engineers.
  25. Abhishek, R., Kumar, G. S., Sapru, R. (2015). Wettability alteration in carbonate reservoirs using nanofluids. Petroleum Science and Technology, 33(7), 794.801.
  26. Moghaddam, R. N., Bahramian, A., Fakhroueian, Z., et al. (2015). Comparative study of using nanoparticles for enhanced oil recovery: Wettability alteration of carbonate rocks. Energy & Fuels, 29(4), 2111-2119.
  27. Suleimanov, B. A., Ismayilov, F. S., Veliyev, E. F., Dyshin, O. A. (2013). The influence of light metal nanoparticles on the strength of polymer gels used in oil industry. SOCAR Proceedings, 2, 24-28.
  28. Wasan, D. T., Nikolov, A. D. (2003). Spreading of nanofluids on solids. Nature, 423, 156-159.
  29. Zhang, H., Ramakrishnan, T. S., Nikolov, A. D., Wasan, D. T. (2016). Enhanced oil recovery (EOR) driven by nanofilm structural disjoining pressure: flooding experiments and microvisualization. Energy & Fuels, 30(4), 2771-2779.
  30. Suleimanov, B. A., Abbasov, H. F. (2016). Effect of copper nanoparticle aggregation on the thermal conductivity of nanofluids. Russian Journal of Physical Chemistry A, 90, 420–428.
  31. Abbasov, H. F. (2019). Determination of nanolayer thickness and effective thermal conductivity of nanofluids. Journal of Dispersion Science and Technology, 40(4), 594-603.
  32. Abbasov, H. F. (2020). Modeling of anisotropic thermal conductivity of ferrofluids. Journal of Dispersion Science and Technology, 41(7), 1030-1036.
  33. Liu, Y., Wang, A., Freeman, J. J. (2009). Raman, MIR, and NIR spectroscopic study of calcium sulfates: gypsum, bassanite, and anhydrite. In: 40th Lunar & Planetary Sciences Conference, Houston.
  34. Riemenschneider, J. (2011). Spectroscopic investigations on pure water and aqueous salt solutions in the mid infrared region. Thesis for the degree doctor rerum naturalium (Dr. rer. nat.) of the Faculty of Sciences University of Rostock, Rostock.
  35. Sulaiman, M., Rahman A. A., Mohamed, N. S. (2013). Structural, thermal and conductivity studies of magnesium nitrate – alumina composite solid electrolytes prepared via sol-gel method. International Journal of Electrochemical Science, 8, 6647–6655.
  36. Suleimanov, B. A., Abbasov, H. F., Ismayilov, R. H., et al. (2017). Thermophysical properties of nano- and microfluids with [Ni5(μ5-pppmda)4Cl2] metal string complex particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 513(5), 41-50.
  37. Suleimanov, B. A., Abbasov, H. F., Valiyev, F. F., et al. (2018). Thermal-conductivity enhancement of microfluids with Ni33-ppza)4Cl2 metal string complex particles. Journal of Heat Transfer, 141(1), 012404.
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DOI: 10.5510/OGP20220300705

E-mail: Baghir.Suleymanov@socar.az


R. T. Akhmetov1, R. U. Rabaev2, L. S. Kuleshova1, V. V. Mukhametshin1, L. Z. Samigullina1

1Institute of Oil and Gas, Ufa State Petroleum Technological University (branch in the City of  Oktyabrsky), Oktyabrsky, Russia; 2Ufa State Petroleum Technological University, Ufa, Russia

Adsorbed residual oil saturation and phase permeability relationship in productive formations of Western Siberias


The paper points out that the permeability for oil at residual water saturation (the starting point of the single phase flow curve for oil) is determined by the adsorbed residual oil saturation of the reservoir. A formula linking the adsorbed residual oil saturation coefficient with the phase permeability for oil with residual water saturation has been obtained. It is noted that the adsorbed residual oil saturation is also closely related to the residual water saturation of the reservoir. Such a connection is carried out through the formation shaliness. The proposed methodology allows structuring the residual oil saturation by type and mobility degree, as well as predicting the mobile oil residual reserves distribution to justify the recovery technologies.

Keywords: types of residual oil; relative phase permeability; productive reservoir.

The paper points out that the permeability for oil at residual water saturation (the starting point of the single phase flow curve for oil) is determined by the adsorbed residual oil saturation of the reservoir. A formula linking the adsorbed residual oil saturation coefficient with the phase permeability for oil with residual water saturation has been obtained. It is noted that the adsorbed residual oil saturation is also closely related to the residual water saturation of the reservoir. Such a connection is carried out through the formation shaliness. The proposed methodology allows structuring the residual oil saturation by type and mobility degree, as well as predicting the mobile oil residual reserves distribution to justify the recovery technologies.

Keywords: types of residual oil; relative phase permeability; productive reservoir.

References

  1. Dmitrievsky, A. N. (2017). Resource-innovative strategy for the development of the Russian economy. Oil Industry, 5, 6-7.
  2. Krylov, A. P. (1974). About some issues of the oil recovery problem in connection with its study. Moscow: Oil Industry.
  3. Shchelkachev, V. N. (2004). The most important principles of oil refining: 75 years of experience. Moscow: Oil and Gas, Gubkin University.
  4. Zakirov, S. N., Indrupsky, I. M., Zakirov, E. S., et al. (2009). New principles and technologies for the development of oil and gas fields. Part 2. Moscow-Izhevsk: Institute of Computer Research.
  5. Veliyev, E. F., Aliyev, A. A., Mammadbayli, T. E. (2021). Machine learning application to predict the efficiency of water coning prevention techniques implementation. SOCAR Procceedings, 1, 104-113.
  6. Khakimzyanov, I. N., Mukhametshin, V. Sh., Lifantyev, A. V., et al. (2022). Regulation of development of the main deposit of the рashi horizon Bavlinskoye field by limiting water injection. SOCAR Proceedings, SI1, 45-56.
  7. Khisamiev, T. R., Bashirov, I. R., Mukhametshin, V. Sh., et al. (2021). Results of the development system optimization and increasing the efficiency of carbonate reserves extraction of the turney stage of the Chetyrmansky deposit. SOCAR Proceedings, SI2, 131-142.
  8. Abbasov, A. A., Abbasov, E. M., Ismayilov, Sh. Z., Suleymanov, A. A. (2021). Waterflooding efficiency estimation using capacitance-resistance model with non-linear productivity index. SOCAR Procеedings, 3, 45-53.
  9. Mukhametshin, V. Sh. (2022). Oil flooding in carbonate reservoirs management. SOCAR Proceedings, SI1, 38-44.
  10. Mukhametshin, V. V., Kuleshova, L. S. (2022). Improving the lower cretaceous deposits development efficiency in Western Siberia employing enhanced oil recovery. SOCAR Proceedings, SI1, 9-18.
  11. Ivanova, M. M., Dementyev, L. F., Cholovsky, I. P. (2014). Oil and gas field geology and geological bases of oil and gas field development. Moscow: Alliance.
  12. Tokarev, M. A. (1983). Assessment and use of the characteristics of the geological heterogeneity of the productive formation. Ufa: UNI.
  13. Kochetkov, A. V., Fattakhov, I. G., Mukhametshin, V. V., et al. (2022). Mathematical model of linear and non-linear proppant concentration increase during hydraulic fracturing – a solution for sequential injection of a number of proppant types. Journal of Mining Institute, 254(2), 210-216.
  14. Grishchenko, V. A., Gareev, R. R., Tsiklis, I. M., et al. (2021). Expanding the amount of preferential royalty facilities with hard-to-recover oil reserves. SOCAR Proceedings, SI2, 8-18.
  15. Grishchenko, V. A., Pozdnyakova, T. V., Mukhamadiyev, B. M., et al. (2021). Improving the carbonate reservoirs development efficiency on the example of the tournaisian stage deposits. SOCAR Proceedings, SI2, 238-247.
  16. Mikhailov, N. N. (2011). Petrophysical support for novel technologies for the re-extraction of residual oil from manmodified pools. Karotazhnik, 7(205), 126-137.
  17. Veliyev, E. F. (2021). Application of amphiphilic block-polymer system for emulsion flooding. SOCAR Proceedings, 3, 78-86.
  18. Mukhametshin, V. Sh. (2022). Oil recovery factor express evaluation during carbonate reservoirs development in natural regimes. SOCAR Proceedings, SI1, 27-37.
  19. Kuleshova, L. S., Mukhametshin, V. Sh. (2022). Research and justification of innovative techniques employment for hydrocarbons production in difficult conditions. SOCAR Proceedings, SI1, 71-79.
  20. Grishchenko, V. A., Tsiklis, I. M., Mukhametshin, V. Sh., Yakupov, R. F. (2021). Methodological approaches to increasing the flooding system efficiency at the later stage of reservoir development. SOCAR Proceedings, SI2, 161-171.
  21. Veliyev, E. F. (2020). Mechanisms of Polymer retention in porous media. SOCAR Procåedings, 3, 126-134.
  22. Mikhailov, N. N. (1992). Residual oil saturation of the developed. Moscow: Nedra.
  23. Mikhailov, N. N., Semenova, N. A., Sechina, L. S. (2010). The conditions of microstructure wetting forming and their influence on filtration-measurement characteristics of productive strata. Georesources, Geoenergetics, Geopolitics, 1(1), 30.
  24. Mikhailov, N. N., Sechina, L. S., Gurbatova, I. P. (2011). Wettability indicators in the porous environment and dependence between them. Georesources, Geoenergetics, Geopolitics, 1(3), 10.
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  26. Brooks, R. H., Corey, A. T. (1966). Properties of porous media affecting fluid flow. Journal of the Irrigation and Drainage Division, 92, 61-90.
  27. Cheremisin, N. A., Sonich, V. P., Baturin, Yu. E., Drozdov, V. A. (1997). Conditions for the formation of residual oil saturation in polymictic reservoirs during their flooding. Oil Industry, 9, 40-45.
  28. Mikhailov, N. N., Sechina, L. S., Motorova, K. A. (2012). Role of clay minerals in formation of the adsorption-connected oil in rock-collectors of hydrocarbonic raw materials. Georesources, Geoenergetics, Geopolitics, 1(5), 51.
  29. Purcell, W. R. (1949). Capillary pressures - their measurement using mercury and the calculation of permeability therefrom. Trans AIME, 186, 39–48.
  30. Mukhametshin, V. V., Akhmetov, R. T., Kuleshova, L. S., Grezina, O. A. (2021). Analytical links between porosity and permeability correlations of productive strata of Western Siberia based on a generalized mathematical model of capillary curves. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 332(8), 135-141.
  31. Akhmetov, R. T., Malyarenko, A. M., Kuleshova, L. S., et al. (2021). Quantitative assessment of hydraulic tortuosity of oil and gas reservoirs in Western Siberia based on capillarimetric studies. SOCAR Proceedings, 2, 77-84.
  32. Akhmetov, R. T., Kuleshova, L. S., Mukhametshin, V. V. (2019). Application of the Brooks-Corey model in the conditions of lower cretaceous deposits in terrigenous reservoirs of Western Siberia. IOP Conference Series: Materials Science and Engineering, 560, 012004.
  33. Akhmetov, R. T., Mukhametshin, V. V. (2018). Estimation of displacement coefficient with due account for hydrophobization of reservoir using geophysical data of wells. IOP Conference Series: Earth and Environmental Science, 194, 062001.
  34. Akhmetov, R. T., Mukhametshin, V. V., Andreev, A. V. (2017). A quantitative assessment method of the productive formation wettability indicator according to the data of geophysical surveys. SPE-187907-MS. In: SPE Russian Petroleum Technology Conference. Society of Petroleum Engineers.
  35. Akhmetov, R. T., Kuleshova, L. S., Mukhametshin, V. V., et al. (2022). Substantiation of the absolute permeability model taking into account the pore tortuosity factor according to the capillarimetric investigations results. SOCAR Proceedings, SI1, 1-8.
  36. Akhmetov, R. T., Kuleshova, L. S., Veliyev, E. F., et al. (2022). Substantiation of an analytical model of reservoir pore channels hydraulic tortuosity in Western Siberia based on capillary research data. Bulletin of the Tomsk Polytechnic University. Geo Àssets Engineering, 333(7), 86–95.
  37. Akhmetov, R. T., Kuleshova, L. S., Mukhametshin, V. V., et al. (2022). Substantiation of the absolute permeability model taking into account the pore tortuosity factor according to the capillarimetric investigations results. SOCAR Proceedings, SI1, 1-8.
  38. Akhmetov, R. T., Kuleshova, L. S., Rabaev, R. U., et al. (2021). Filtering pore channels distribution density in Western Siberia. SOCAR Proceedings, SI2, 221-228.
  39. Grishchenko, V. A., Rabaev, R. U., Asylgareev, I. N., et al. (2021). Methodological approach to optimal geological and technological characteristics determining when planning hydraulic fracturing at multilayer facilities. SOCAR Proceedings, SI2, 182-191.
  40. Akhmetov, R. T., Mukhametshin, V. V., Kuleshova, L. S., Grezina, O. A. (2021). Production facilities grouping based on the parameters of the capillary pressure curves generalized model on the example of Western Siberia oil fields. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 332(11), 89–97.
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DOI: 10.5510/OGP20220300706

E-mail: vv@of.ugntu.ru


А. G. Gurbanov1, S. J. Rzayeva2

1Umid Babek Operation Company (UBOC), Baku, Azerbaijan; 2«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan

Self-sustaining organic acid system for treatment of terrigenous reservoirs


A method for acid treatment of the bottom zone of a terrigenous heterogeneous reservoir, including isolation of highly permeable reservoir areas with a foam solution formed in the reservoir and subsequent treatment of low-permeability reservoir zones with an organic acid systemhas been developed. The composition of the organic acid system is selected depending on the carbonate content of the bottom well area. The efficiency of the method is increased by increasing the foam system stability, the depth and thickness coverage of the formation, and by reducing corrosion activity as a result of the use of organic acid systems. As carbonate rocks dissolve, the reservoir and filtration characteristics of the formation will increase.

Keywords: acid treatment; citric acid; whey; polymer; crosslinker; foam system; stability; carbonate content; permeability.

A method for acid treatment of the bottom zone of a terrigenous heterogeneous reservoir, including isolation of highly permeable reservoir areas with a foam solution formed in the reservoir and subsequent treatment of low-permeability reservoir zones with an organic acid systemhas been developed. The composition of the organic acid system is selected depending on the carbonate content of the bottom well area. The efficiency of the method is increased by increasing the foam system stability, the depth and thickness coverage of the formation, and by reducing corrosion activity as a result of the use of organic acid systems. As carbonate rocks dissolve, the reservoir and filtration characteristics of the formation will increase.

Keywords: acid treatment; citric acid; whey; polymer; crosslinker; foam system; stability; carbonate content; permeability.

References

  1. Shafiq, M. U., Mahmud, H. B. (2017). Sandstone matrix acidizing knowledge and future development. Journal of Petroleum Exploration and Production Technology, 7, 1205–1216.
  2. Shafiq, M. U., Ben Mahmud, H. K., Hamid, M. A. (2015). Comparison of buffer effect of different acids during sandstone acidizing. IOP Conference Series: Materials Science and Engineering, 78, 012008.
  3. Glushchenko, V. N., Silin, M. A. (2010). Oilfield chemistry. T.4. Acid treatment of wells. Moscow: Intercontact Nauka.
  4. Abdelfatah, E., Bang, S., Pournik, M., et al. (2017, November). Acid diversion in carbonates with nanoparticlesbased in situ gelled acid. SPE-188188-MS. In: Abu Dhabi International Petroleum Exhibition & Conference. Society of Petroleum Engineers.
  5. Shakhverdiev, A. Kh., Panakhov, G. M., Suleimanov, B. A., Abbasov, E. M. (2000). Method of acid treatment of bottom-hole oil formation zone. RU Patent № 2145381.
  6. Shefer, A. Z., Merkulov, V. P., Intyashin, A. D. (1975). Ispol'zovaniye otkhodov proizvodstva zhirnykh kislot dlya povysheniya priyemistosti nagnetatel'nykh skvazhin. Neftepromyslovoye Delo, 4, 30-32.
  7. Rabie, A. I., Saber, M. R., Nasr El-Din, H. A. (2015, April). A new environmentally friendly acidizing fluid for HP/HT matrix acidizing treatments with enhanced product solubility. SPE-173751-MS. In: SPE International Symposium on Oilfield Chemistry. Society of Petroleum Engineers.
  8. Hong, L. V., Ben Mahmud, H. (2019). A preliminary screening and characterization of suitable acids for sandstone matrix acidizing technique: a comprehensive review. Journal of Petroleum Exploration and Production Technology, 9, 753-778.
  9. Blinkova, E. V., Eliseev, E. I. (2005). Dissolution of calcium carbonate in aqueous solutions of acetic acid. Russian Journal of Applied Chemistry, 78(7), 1064-1066.
  10. Kasenova, G. M. (1985). Svoystva smesey karbonovykh kislot i produktov ikh neytralizatsii karbonatami. Neftepromyslovoye Delo i Transport Nefti, 4, 15-16.
  11. Buijse, M., de Boer, P., Breukel, B., Burgas, G. (2004). Organic acids in carbonate acidizing. SPE-82211-PA. SPE Production & Operations, 19(3), 128-134.
  12. Chang, F. F., Nasr-El-Din, H. A., Lindvig, T., Qiu, X. W. (2008, September). Matrix acidizing of carbonate reservoirs using organic acids and mixture of HCl and organic acids. SPE-116601-MS. In: SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
  13. Saber, M. R., Rabie, A., Nasr-El-Din, H. A. (2015, October). A new technique to increase the performance of organic acids to stimulate carbonate reservoirs at high acid concentrations. SPE-175192-MS. In: SPE Kuwait Oil and Gas Show and Conference. Society of Petroleum Engineers.
  14. Alhamad, L., Alrashed, A., Munif, E., Miskimins, J. (2020). Organic acids for stimulation. SPE-199291-PA. SPE Production and Operation, 35(4), 952-978.
  15. He, L., Dan-feng, X., Ke-ming, F., et al. (2009). Successful acid stimulation in acid-sensitive reservoirs. SPE-121014-MS. In: Asia Pacific Oil and Gas Conference & Exhibition. Society of Petroleum Engineers.
  16. Burgos, G., Birch, G., Buijse, M. (2004, February). Acid fracturing with encapsulated citric acid. SPE-86484-MS. In: SPE International Symposium and Exhibition on Formation Damage Control. Society of Petroleum Engineers.
  17. Al-Harbi, B. G., Al Dahlan, M. N., Khaldi, M. H. (2012, February). Aluminum and iron precipitation during sandstone acidizing using organic-HF acids. SPE-151781-MS. In: SPE International Symposium and Exhibition on Formation Damage Control. Society of Petroleum Engineers.
  18. Yang, F. (2012) Acidizing of sandstone reservoirs using HF and organic acids. PhD master’s thesis. Texas: Texas A&M University.
  19. Yang, F., Nasr-El-Din, H. A., Harbi, B. A. (2012, May) Acidizing sandstone reservoirs using HF and organic acids. SPE-157250-MS. In: SPE International Production and Operations Conference & Exhibition. Society of Petroleum Engineers.
  20. Van Domelen, M. S., Reddingius, A. A., Faber, M. J., Buijse, M. A. (1997, June) High temperature acid stimulation offshore the Netherlands. SPE-38171-MS. In: SPE European Formation Damage Conference. Society of Petroleum Engineers.
  21. Andotra, G. (2014) Investigating the use of chelating agents for clay dissolution and sandstone acidizing purposes. PhD master’s thesis. Texas: Texas A&M University.
  22. Dmitruk, V. V., Singurov, A. A., Kononov, A. V. (2011). New solution for an intensification "senoman" wells and experimental-industrial tests. Oil and Gas Business, 5, 196-205.
  23. Dmitruk, V. V., Fedoseyev, A. P., Dzhanagayev, V. S. i dr. (2012). Primeneniye limonnoy kisloty pri intensifikatsii dobychi uglevodorodov. Nauka i Tekhnika v Gazovoy Promyshlennosti, 1(49), 27-32.
  24. Kustyshev, A. V., Singurov, A. A., Panikarovskij, E. V., et al. (2014). Processing of bottomhole of low-cemented terrigenous bed at abnormally low bed pressure. RU Patent № 2528803.
  25. Rzayeva, S. J. (2020). Selective insulation of water flows in a well based on the use of production waste. SOCAR Proceedings, 3, 118-125.
  26. Kazymov, Sh. P., Aliyev, YA. M., Rzayeva, S. Dzh. i dr. (2000). Sposob obrabotki prizaboynoy zony neftyanykh skvazhin. Patent Azerbaydzhanskoy Respubliki İ 2000 0030.
  27. Suleimanov, B. A., Rzayeva, S. J., Tulesheva, G. D. (2018). Method for acid treatment of a bottomhole zone in a heterogeneous formation. Eurasian patent EA 030395.
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DOI: 10.5510/OGP20220300707

E-mail: rsabina73@mail.ru


А. A. Abbasov1, Sh. Z. Ismayilov2, A. A. Suleymanov2, I. N. Aliyev2, B. F. Novruzaliyev3

1SOCAR, Baku, Azerbaijan; 2Azerbaijan State Oil and Industry University, Baku, Azerbaijan; 3«OilGasScientificResearchProject» Institute, SOCAR, Baku, Azerbaijan

Gas lifted well performance evaluation based on operational parameters’ fluctuations


The paper describes the gas lifted well performance evaluation ability based on operational parameters’ fluctuations analysis. Experimental laboratory research showed that the optimum gas-liquid lift performance correlates with minimal fluctuation of flowrate and pressures. Also, trials in the «Neft Dashlary» oilfield were conducted. Gas lifted well’s flowing tubing head pressure fluctuations were evaluated at different lift gas injection rates – below, above, and at the optimum gas injection rates. The results of field trials show that at optimum gas lifter well performance, the tubing head pressure fluctuation amplitude reduction and frequency increase is observed. This is in line with theoretical prediction and lab experiments conducted. It is shown that gas lifted and naturally flowing wells’ performance quick evaluation is doable during normal operation. The introduced method allows timely detection of well performance deviation from optimal. Necessary measures can be taken to optimize the wells without conducting additional surveillance.

Keywords: well; gas lift; flow rate; operational parameters; well performance.

The paper describes the gas lifted well performance evaluation ability based on operational parameters’ fluctuations analysis. Experimental laboratory research showed that the optimum gas-liquid lift performance correlates with minimal fluctuation of flowrate and pressures. Also, trials in the «Neft Dashlary» oilfield were conducted. Gas lifted well’s flowing tubing head pressure fluctuations were evaluated at different lift gas injection rates – below, above, and at the optimum gas injection rates. The results of field trials show that at optimum gas lifter well performance, the tubing head pressure fluctuation amplitude reduction and frequency increase is observed. This is in line with theoretical prediction and lab experiments conducted. It is shown that gas lifted and naturally flowing wells’ performance quick evaluation is doable during normal operation. The introduced method allows timely detection of well performance deviation from optimal. Necessary measures can be taken to optimize the wells without conducting additional surveillance.

Keywords: well; gas lift; flow rate; operational parameters; well performance.

References

  1. Mirzajanzade, A. Kh., Khasanov, M. M., Bakhtizin, R. N. (1999). Studies on modeling of complex systems of oil production. Nonlinearity, nonequilibrium, heterogeneity. Ufa: Gilem.
  2. Mirzajanzade, A. Kh., Filippov, V. P., Ametov, I. M. (1998). Systematic methods in oil production. Moscow: RMNTC «Nefteotdacha».
  3. Hernandez, A. (2016). Fundamentals of gas lift engineering. Elsevier, Gulf Professional Publishing.
  4. Golan, M., Whitson, C. H. (1996). Well performance. Prentice-Hall.
  5. Beggs, H. D. (2003). Production optimization. Petroskills.
  6. Brill, J. P., Mukherjee, H. (1999). Multiphase flow in wells. Society of Petroleum Engineers.
  7. Economides, M. J., Hill, A. D., Ehlig-Economides, Ch. (1994). Petroleum production systems. Prentice Hall.
  8. Fairuzov, Y., Guerrero-Sarabia, C., Carmona-Diaz, R., et al. (2004, September). Stability maps for continuous gas-lift wells: A new approach to solving an old problem. SPE-90644-MS. In: SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
  9. Gang, Z., Golan, M. (1989). Criteria for operation stability of gas lift wells. In: SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
  10. Saepudin, D., Soewono, E., Sidarto, K., et al. (2007). An investigation on gas lift performance curve in an oil-producing well. International Journal of Mathematics and Mathematical Sciences, 7, ID 81519.
  11. Slupphaug, O., Bjune, B. (2006, September). Active slug management. SPE-96644-MS. In: SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
  12. Alhanati, F., Schmidt, Z., Doty, D., Lagerlef, D. (1993). Continuous gas-lift instability: Diagnosis, criteria and solutions. Society of Petroleum Engineers.
  13. Asheim, H. (2000). Criteria for gas-lift stability. SPE-16468-PA. Journal of Petroleum Technology, 40(11), 1452-1456. Society of Petroleum Engineers.
  14. Guerrero-Sarabia, I., Fairuzov, Y. (2013). Linear and non-linear analysis of flow instability in gas-lift wells. Journal of Petroleum Science and Engineering, 108, 162-171.
  15. Hu, B., Golan, M. (2003, October). Gas-lift instability resulted production loss and its remedy by feedback control: Dynamic simulation results. SPE-84917-MS. In: SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers.
  16. Jensen, J. L., Lake, L. W., Corbett, P. W. M., Goggin, D. J. (2000). Statistics for petroleum engineers and geoscientists. Amsterdam: Elsevier.
  17. Mirzajanzade, A. Kh., Aliev, N. A., Yusifzade, Kh. B., et al. (1997). Fragments on development of. offshore oil and gas fields. Baku: Elm.
  18. Weaver, W., Timoshenko, S. P., Young, D. H. (1990). Vibration problems in engineering. New York: John Wiley & Sons.
  19. Mirzajanzade, A. Kh., Kerimov, Z. G., Kopeykis, M. G. (1976). The theory of fluctuations in the oilfield business. Baku: Maarif.
  20. Xu, Z. G., Golan, M. (1999). Criteria for operation stability of gas lift. Society of Petroleum Engineers.
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DOI: 10.5510/OGP20220300708

E-mail: petrotech@asoiu.az


G. G. Suleymanov, H. G. Ismayilova, E. R. Qasumov

Azerbaijan State Oil and Industry University, Baku, Azerbaijan

Main direction for improving the use of oil and qas fields


The creation of an effective system for the application of innovations in the development of oil and gas fields (OGF) at the present stage requires an appropriate innovation policy. There is a need to develop a strategy and methodology for the formation of approaches for the effective implementation of innovations in the development of oil and gas fields and ensuring their economic efficiency, both in the domestic and global markets. The development of innovative and methodological foundations, methods of integrated modeling, management and evaluation of the technical and economic efficiency of introducing innovative approaches in the process of OGF development is an important scientific and practical task.

Keywords: innovation; oil; gas; geological and technical measures; effective management.

The creation of an effective system for the application of innovations in the development of oil and gas fields (OGF) at the present stage requires an appropriate innovation policy. There is a need to develop a strategy and methodology for the formation of approaches for the effective implementation of innovations in the development of oil and gas fields and ensuring their economic efficiency, both in the domestic and global markets. The development of innovative and methodological foundations, methods of integrated modeling, management and evaluation of the technical and economic efficiency of introducing innovative approaches in the process of OGF development is an important scientific and practical task.

Keywords: innovation; oil; gas; geological and technical measures; effective management.

References

  1. Qasumov, E. R. (2012). Sovershenstvovanie ochenki effektivnosti vnedreniya innovachiy pri razrabotke qazovyx mestorojdeniy. Dissertachiya na soiskaniye uchenoy stepeni kanditata ekonomicheskix nauk. Stavropol: FQBOU VPO «Stavropolskiy Qosudarstvenniy Universitet».
  2. Drozdenko, Yu. A. (2018). Strateqicheskoye upravleniye innovachiyami. Eqo sushnost I znachenie dlya predpriyatiya. Sbornik statey II Mejdunarodnoy nauchno-prakticheskoy konferenchii «Innovachionnoye razvitiye nauki i obrazovaniya». Penza: MCNS «Nauka i Prosvesheniye».
  3. Qasumov, E. R. (2012). Ochenka effektivnosti vnedreniya innovachiy v nefteqazovoy otrasli. Saarbrucken, Deutschland: LAP LAMBERT Academic Publishing.
  4. Alyabina, E. V., Ivanova, Q. S. (2017). Vozmojnosti vnedreniya orqanizachionnix innovachii na predpriyatiyax nefteqazovix kompleks. Nauchniy jurnal Possiyskoqo Qazovoqo Obshestva, 4, 13-22.
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DOI: 10.5510/OGP20220300709

E-mail: ismayilova.hecer@bk.ru


V. A. Grishchenko1, V. V. Mukhametshin2, R. N. Bakhtizin2, Yu. V. Zeigman2, L. S. Kuleshova1, R. F. Yakupov1, T. R. Vafin1

1Institute of Oil and Gas, Ufa State Petroleum Technological University (branch in the city of Oktyabrsky), Oktyabrsky, Russia; 2Ufa State Petroleum Technological University, Ufa, Russia

Methodical approach to substantiation of the strategy for the development of residual oil reserves at the final stage of development, taking into account facies analysis


The article considers and solves the problem of finding the optimal strategy for the development of terrigenous deposits of the Bobrikovsko-Radaev horizon of one of the deposits of the Ural-Volga region. Based on the analysis of the behavior of the curves obtained during geophysical surveys in more than three thousand wells, four main types of facies zones were identified, characterized by different porosity and permeability properties and formed development systems. As part of the analysis of the reservoir pressure maintenance system, a direct influence of reservoir properties on the efficiency of waterflooding was established, which made it possible to develop an optimization strategy and the formation of new injection sites. Using the method of multiple regression analysis, two statistical models have been obtained – the reservoir properties model and the facies model, which make it possible to quickly assess the recovery factor and select the optimal development system for fields with a lesser degree of knowledge.

Keywords: oil field development; geological structure; facies model; hydraulic fracturing; horizontal wells; hydrodynamic model; multiple regression analysis.

The article considers and solves the problem of finding the optimal strategy for the development of terrigenous deposits of the Bobrikovsko-Radaev horizon of one of the deposits of the Ural-Volga region. Based on the analysis of the behavior of the curves obtained during geophysical surveys in more than three thousand wells, four main types of facies zones were identified, characterized by different porosity and permeability properties and formed development systems. As part of the analysis of the reservoir pressure maintenance system, a direct influence of reservoir properties on the efficiency of waterflooding was established, which made it possible to develop an optimization strategy and the formation of new injection sites. Using the method of multiple regression analysis, two statistical models have been obtained – the reservoir properties model and the facies model, which make it possible to quickly assess the recovery factor and select the optimal development system for fields with a lesser degree of knowledge.

Keywords: oil field development; geological structure; facies model; hydraulic fracturing; horizontal wells; hydrodynamic model; multiple regression analysis.

References

  1. Muslimov, R. Kh. (2009). Features of exploration and development of oil fields in a market economy. Kazan: FEN.
  2. Kontorovich, A. E. (2016). Global problems of oil and gas and a new paradigm for the development of the Russian oil and gas complex. Science First-hand, 1(67), 6-17.
  3. Gazizov, A. A., Gazizov, A. Sh., Bogdanova, S. A. (2014). High-tech technologies of oil production. Kazan: Center of Innovative Technologies.
  4. Muslimov, R. Kh. (2021). The experience of the Republic of Tatarstan in the rational use of oil resources of the subsoil (the past and thoughts on poor development). Kazan: FEN.
  5. Ibragimov, N. G., Ismagilov, F. Z., Musabirov, M. Kh., Abusalimov, E.M. (2014). Analysis of well stimulation pilot projects in Tatneft OAO. Oil Industry, 7, 40-43.
  6. Muslimov, R. Kh. (2020). About the new paradigm of Academician A.E. Kontorovich - the development of the Russian oil and gas complex. In: international scientific and practical conference «On the new paradigm of the development of oil and gas geology». Kazan: Ikhlas Publ.
  7. Yakupov, R. F., Khakimzyanov, I. N., Mukhametshin, V. V., Kuleshova, L.S. (2021). Hydrodynamic model application to create a reverse oil cone in water-oil zones. SOCAR Proceedings, 2, 54-61.
  8. Fattakhov, I. G., Kuleshova, L. S., Bakhtizin, R. N., et al. (2021). Complexing the hydraulic fracturing simulation results when hybrid acid-propant treatment performing and with the simultaneous hydraulic fracture initiation in separated intervals. SOCAR Proceedings, SI2, 103-111.
  9. Khakimzyanov, I. N., Mukhametshin, V. Sh., Bakhtizin, R. N., Sheshdirov, R. I. (2021). Determination of well spacing volumetric factor for assessment of final oil recovery in reservoirs developed by horizontal wells. SOCAR Proceedings, 2, 47-53.
  10. Ibragimov, N. G., Musabirov, M. Kh., Yartiev, A. F. (2014). Effectiveness of well stimulation technologies package developed by Tatneft OAO. Oil Industry, 7, 44-47.
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  20. Mukhametshin, V. V. (2021). Improving the efficiency of managing the development of the West Siberian oil and gas province fields on the basis of differentiation and grouping. Russian Geology and Geophysics, 62(12), 1373–1384.
  21. Grishchenko, V. A., Asylgareev, I. N., Bakhtizin, R. N., et al. (2021). Methodological approach to the resource base efficiency monitoring in oil fields development. SOCAR Proceedings, SI2, 229-237.
  22. Veliyev, E. F., Aliyev, A. A., Mammadbayli, T. E. (2021). Machine learning application to predict the efficiency of water coning prevention techniques implementation. SOCAR Procceedings, 1, 104-113.
  23. Mingulov, I. Sh., Valeev, M. D., Mukhametshin, V. V., et al. (2021). Study of temperature and flow rate influence on the viscosity of oil emulsions. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 332(10), 69–76.
  24. Suleimanov, B. A., Rzayeva, S. J., Akhmedova, U. T. (2021). Self-gasified biosystems for enhanced oil recovery. SOCAR Proceedings, 3, 36–44.
  25. Stabinskas, A. P., Sultanov, Sh. Kh., Mukhametshin, V. Sh., et al. (2021). Evolution of hydraulic fracturing fluid: from guar systems to synthetic gelling polymers. SOCAR Proceedings, SI2, 172-181.
  26. Veliyev, E. F. (2020). Review of modern in-situ fluid diversion technologies. SOCAR Proceedings, 2, 50-66.
  27. Kuleshova, L. S., Fattakhov, I. G., Sultanov, Sh. Kh., et al. (2021). Experience in conducting multi-zone hydraulic fracturing on the oilfield of PJSC «Tatneft». SOCAR Proceedings, SI1, 68-76.
  28. Ibragimov, N. G., Musabirov, M. Kh., Yartiev, A. F. (2015). Tatneft's experience in commercialization of importsubstituting well stimulation technologies. Oil Industry, 8, 86-89.
  29. Veliyev, E. F. (2021). Application of amphiphilic block-polymer system for emulsion flooding. SOCAR Proceedings, 3, 78-86.
  30. Muslimov, R. Kh. (2004). Ways to increase oil recovery in oil fields that have been technogenically altered during long-term in-circuit flooding. In: international conference «Fundamental problems of oil and gas fields development, extraction and transportation of hydrocarbon raw materials». Moscow: GEOS.
  31. Khisamiev, T. R., Bashirov, I. R., Mukhametshin, V. Sh., et al. (2021). Results of the development system optimization and increasing the efficiency of carbonate reserves extraction of the turney stage of the Chetyrmansky deposit. SOCAR Proceedings, SI2, 131-142.
  32. Rogachev, M. K., Mukhametshin, V. V. (2018). Control and regulation of the hydrochloric acid treatment of the bottomhole zone based on field-geological data. Journal of Mining Institute, 231, 275-280.
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  35. Mukhametshin, V. Sh., Khakimzyanov, I. N., Bakhtizin, R. N., Kuleshova, L. S. (2021). Differentiation and grouping of complex-structured oil reservoirs in carbonate reservoirs in development management problems solving. SOCAR Proceedings, SI1, 88-97.
  36. Mukhametshin, V. V., Andreev, V. E. (2018). Increasing the efficiency of assessing the performance of techniques aimed at expanding the use of resource potential of oilfields with hard-to-recover reserves. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 329(8), 30–36.
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  41. Grishchenko, V. A., Yakupov, R. F., Mukhametshin, V. Sh., et al. (2021). Localization and recovery strategy of residual reserves the pashian horizon of the Tuymazinskoye oil field at the final stage of development. Oil Industry, 5, 103-107.
  42. Grishchenko, V. A., Rabaev, R. U., Asylgareev, I. N., et al. (2021). Methodological approach to optimal geological and technological characteristics determining when planning hydraulic fracturing at multilayer facilities. SOCAR Proceedings, SI2, 182-191.
  43. Yakupov, R. F., Mukhametshin, V. Sh., Khakimzyanov, I. N., Trofimov, V. E. (2019). Optimization of reserve production from water oil zones of D3ps horizon of Shkapovsky oil field by means of horizontal wells. Georesursy, 21(3), 55-61.
  44. Yakupov, R. F., Mukhametshin, V. Sh., Tyncherov, K. T. (2018). Filtration model of oil coning in a bottom water-drive reservoir. Periodico Tche Quimica, 15(30), 725-733.
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  46. Grishchenko, V. A., Pozdnyakova, T. V., Mukhamadiyev, B. M., et al. (2021). Improving the carbonate reservoirs development efficiency on the example of the tournaisian stage deposits. SOCAR Proceedings, SI2, 238-247.
  47. Mingulov, Sh. G., Yakupov, R. F. (2013). Injection capacity of wells restoration on group of fields Tuimazinskaya. Oil Industry, 7, 88–91.
  48. Grishchenko, V. A., Tsiklis, I. M., Mukhametshin, V. Sh., Yakupov, R. F. (2021). Methodological approaches to increasing the flooding system efficiency at the later stage of reservoir development. SOCAR Proceedings, SI2, 161-171.
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DOI: 10.5510/OGP20220300710

E-mail: vv@of.ugntu.ru


U. T. Ahmadova

SOCAR Downstream Management LLC, Baku, Azerbaijan

Review of oil recovery techniques using foam systems


The article provides an overview of enhanced oil recovery methods based on the injection of foam systems. In late-stage fields developing, it is necessary to block highly permeable watered formation zones. For this purpose, the use of foaming systems is promising. As a result of blocking high-permeability zones with foam systems, lowpermeability oil-saturated zones are involved in the development. The article considers the foaming mechanism, selection of foam stabilizers, foam migration in the formation. The influence of temperature, mineralization of formation water, the presence of oil on the stability of foam systems are investigated in this review. Experimental studies and field implementation indicate that technologies are very effective. Foam flooding increases the coverage efficiency in heterogeneous reservoirs, thereby increasing the oil recovery ratio. Investigations into this matter are therefore urgent and still ongoing today.

Keywords: foaming systems; stability; polymer; nanoparticles; microphotographs; salinity; displacement ratio; formation coverage; self-generating thermal foams; fractured reservoirs.

The article provides an overview of enhanced oil recovery methods based on the injection of foam systems. In late-stage fields developing, it is necessary to block highly permeable watered formation zones. For this purpose, the use of foaming systems is promising. As a result of blocking high-permeability zones with foam systems, lowpermeability oil-saturated zones are involved in the development. The article considers the foaming mechanism, selection of foam stabilizers, foam migration in the formation. The influence of temperature, mineralization of formation water, the presence of oil on the stability of foam systems are investigated in this review. Experimental studies and field implementation indicate that technologies are very effective. Foam flooding increases the coverage efficiency in heterogeneous reservoirs, thereby increasing the oil recovery ratio. Investigations into this matter are therefore urgent and still ongoing today.

Keywords: foaming systems; stability; polymer; nanoparticles; microphotographs; salinity; displacement ratio; formation coverage; self-generating thermal foams; fractured reservoirs.

References

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DOI: 10.5510/OGP20220300711

E-mail: u.ismayilova@gmail.com


R. R. Kadyrov1, R. U. Rabaev2, V. Sh. Mukhametshin1, V. I. Shchetnikov3, I. F. Galiullina1, A. R. Safiullina1, Z. N. Sagitova1, R. R. Stepanova1

1Ufa State Petroleum Technological University (branch in the city of Oktyabrsky), Oktyabrsky, Russia; 2Ufa State Petroleum Technological University, Ufa, Russia; 3JV «Vietsovpetro», Vung Tau, Vietnam<

Reservoir waters and based on them heavy brines application in oil production


The paper shows that the liquid obtained as a result of reservoir water desalination has a reduced magnesium ions content. Using such a liquid, it is possible to increase the mechanical strength of cement stone, its impermeability, adhesion to casing pipes and the well wall, as well as reduce magnesia corrosion.

Keywords: reservoir water; cement stone; construction lime; cement stone strength.

The paper shows that the liquid obtained as a result of reservoir water desalination has a reduced magnesium ions content. Using such a liquid, it is possible to increase the mechanical strength of cement stone, its impermeability, adhesion to casing pipes and the well wall, as well as reduce magnesia corrosion.

Keywords: reservoir water; cement stone; construction lime; cement stone strength.

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  8. Grishchenko, V. A., Pozdnyakova, T. V., Mukhamadiyev, B. M., et al. (2021). Improving the carbonate reservoirs development efficiency on the example of the tournaisian stage deposits. SOCAR Proceedings, SI2, 238-247.
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  23. Veliyev, E. F., Aliyev, A. A., Mammadbayli, T. E. (2021). Machine learning application to predict the efficiency of water coning prevention techniques implementation. SOCAR Procceedings, 1, 104-113.
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  25. Grishchenko, V. A., Asylgareev, I. N., Bakhtizin, R. N., et al. (2021). Methodological approach to the resource base efficiency monitoring in oil fields development. SOCAR Proceedings, SI2, 229-237.
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  30. Veliyev, E. F. (2020). Review of modern in-situ fluid diversion technologies. SOCAR Proceedings, 2, 50-66.
  31. Grishchenko, V. A., Tsiklis, I. M., Mukhametshin, V. Sh., Yakupov, R. F. (2021). Methodological approaches to increasing the flooding system efficiency at the later stage of reservoir development. SOCAR Proceedings, SI2, 161-171.
  32. Grishchenko, V. A., Gareev, R. R., Tsiklis, I. M., et al. (2021). Expanding the amount of preferential royalty facilities with hard-to-recover oil reserves. SOCAR Proceedings, SI2, 8-18.
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  34. Mukhametshin, V. V., Kuleshova, L. S. (2020). On uncertainty level reduction in managing waterflooding of the deposits with hard to extract reserves. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 331(5), 140–146.
  35. Mukhametshin, V. Sh. (2022). Oil flooding in carbonate reservoirs management. SOCAR Proceedings, SI1, 38-44.
  36. Mardashov, D. V., Rogachev, M. K., Zeigman, Yu. V., Mukhametshin, V. V. (2021). Well killing technology before workover operation in complicated conditions. Energies, 14(3), 654.
  37. Veliyev, E. F. (2021). Application of amphiphilic block-polymer system for emulsion flooding. SOCAR Proceedings, 3, 78-86.
  38. Gilyazetdinov, Z. F., Kadyrov, R. R., Salimov, M. Kh., et al. (2000). Grouting cement mortar. RU Patent 2154727.
  39. Babushkin, V. I. (1968). Physico-chemical corrosion processes of concrete and reinforced concrete. Moscow: Stroyizdat.
  40. Grishchenko, V. A., Rabaev, R. U., Asylgareev, I. N., et al. (2021). Methodological approach to optimal geological and technological characteristics determining when planning hydraulic fracturing at multilayer facilities. SOCAR Proceedings, SI2, 182-191.
  41. Mukhametshin, V. V., Andreev, V. E. (2018). Increasing the efficiency of assessing the performance of techniques aimed at expanding the use of resource potential of oilfields with hard-to-recover reserves. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 329(8), 30–36.
  42. Alimkhanov, R., Samoylova I. (2014, October). Application of data mining tools for analysis and prediktion of hydraulic fracturing efficiency for the BV8 reservoir of the Povkh oil field. SPE-171332-MS. In: SPE Russian Oil and Gas Exploration & Production Technical Conference and Exhibition. Society of Petroleum Engineers.
  43. Tokarev, M. A. (1983). Assessment and use of the characteristics of the geological heterogeneity of the productive formation. Ufa: UNI Publishing House.
  44. Bulatov, A. I., Mariampolsky, N. A. (1988). Regulation of technological parameters of grouting solutions. Moscow: Nedra.
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DOI: 10.5510/OGP20220300712

E-mail: vsh@of.ugntu.ru


G. S. Mukhtarova1, R. A. Guliyeva2, R. H. Ahmadova1

1Institute of Petrochemical Processes named after Y.H.Mammadaliyev, Azerbaijan National Academy of Sciences, Baku, Azerbaijan; 2Baku Higher Oil School, Baku, Azerbaijan

Catalytic advances in vacuum gas oil hydrocracking


Hydrocracking still maintains the pivotal role in the industry owing to the production of highly demanded transportation fuels. Having comprised pretreatment of VGO, comparative research onrecent catalysts, this review paper provides athorough picture about all consecutive steps in the hydrocracking process of vacuum gasoil. Discussing recovery of VGO from vacuum residue with minimum sulfur content, the focus was put on the catalyst characterizations and their influence on the conversion of VGO, the yield of middle distillate, gasoline as well asnaphtha. Both zeolite and amorphous catalysts have undergone a comparative analysis interms of their hydrocracking properties as well as catalytic activities during provided conditions. The article also examines the process of hydrocracking of vacuum gas-oil from Baku oils with the participation of modified aluminosilicate catalyst containing Ni, Mo to obtain high-quality raw materials for environmentally friendly diesel fuel and catalytic cracking process. The hydrocracking process of vacuum gas-oil conducted at 3-8 MPa pressure, 400-450 °C temperature range, in a flow-type Hungarian unit with a reactor capacity of 200 ml. During the investigations of temperature on hydrocracking process it was revealed that, when temperature rises from 400 to 460 °С the yield of diesel fraction increases from 35 to 50% wt. The yield of gasoline fraction constitutes 0-6% wt. and the produce of residue fraction decreases from 65% to 45%. With increasing of temperature from 400 °C to 450 °C the amount of sulphur decreases from 0.01% to 0.005% in composition of diesel fraction.

Keywords: vacuum gasoil; hydrocracking; diesel fraction; alumosilicate; catalyst; hydrodesulfurization.

Hydrocracking still maintains the pivotal role in the industry owing to the production of highly demanded transportation fuels. Having comprised pretreatment of VGO, comparative research onrecent catalysts, this review paper provides athorough picture about all consecutive steps in the hydrocracking process of vacuum gasoil. Discussing recovery of VGO from vacuum residue with minimum sulfur content, the focus was put on the catalyst characterizations and their influence on the conversion of VGO, the yield of middle distillate, gasoline as well asnaphtha. Both zeolite and amorphous catalysts have undergone a comparative analysis interms of their hydrocracking properties as well as catalytic activities during provided conditions. The article also examines the process of hydrocracking of vacuum gas-oil from Baku oils with the participation of modified aluminosilicate catalyst containing Ni, Mo to obtain high-quality raw materials for environmentally friendly diesel fuel and catalytic cracking process. The hydrocracking process of vacuum gas-oil conducted at 3-8 MPa pressure, 400-450 °C temperature range, in a flow-type Hungarian unit with a reactor capacity of 200 ml. During the investigations of temperature on hydrocracking process it was revealed that, when temperature rises from 400 to 460 °С the yield of diesel fraction increases from 35 to 50% wt. The yield of gasoline fraction constitutes 0-6% wt. and the produce of residue fraction decreases from 65% to 45%. With increasing of temperature from 400 °C to 450 °C the amount of sulphur decreases from 0.01% to 0.005% in composition of diesel fraction.

Keywords: vacuum gasoil; hydrocracking; diesel fraction; alumosilicate; catalyst; hydrodesulfurization.

References

  1. Fielden, S. (2013). Pump up the volume - using hydrocrackers to increase refinery diesel yields. https://rbnenergy.com/pump-up-the-volume-using-hydrocrackers-to-increase-refinery-diesel-yields.
  2. Fielden, S. (2014). Going to a VGO? – The intermediate feedstock you wish you knew! https://rbnenergy.com/going-toa-vgo-the-intermediate-feedstock-you-wish-you-knew.
  3. Weitkamp, J. (2012). Catalytic hydrocracking-mechanisms and versatility of the process. ChemCatChem, 4(3), 292–306.
  4. Al-Naeem, W. A. (2004). Hydrocracking catalysts for vacuum gas oil and de-metallized oil blend. PhD Thesis. King Fahd University of Petroleum & Minerals.
  5. Scherzer, J., Gruia, A. J. (1996). Hydrocracking science and technology. New York: Marcel Dekker Inc.
  6. Franck, J. P., Le Page, J. F. (1981). Catalysts for the hydrocracking of heavy gas oils into middle distillates. Studies in Surface Science and Catalysis, 7, 792–803.
  7. Pereyma, V. Y., Dik, P. P., Klimov, O. V., Noskov, A. S. (2015). Hydrocracking of vacuum gas oil in the presence of catalysts NiMo/Al2O3–amorphous aluminosilicates and NiW/Al2O3 – amorphous aluminosilicates. Russian Journal of Applied Chemistry, 88(12), 1969–1975.
  8. Ali, M. A., Tatsumi, T., Masuda, T. (2002). Development of heavy oil hydrocracking catalysts using amorphous sililcaalumina and zeolites as catalyst supports. Applied Catalysis A: General, 233, 77-90.
  9. Hashimoto, Y., Enomoto, T., Honna, K., et al. (2002). Development of zeolite-based catalyst for resid hydrocracking. Petroleum Chemistry Division Preprints, 47(4), 351.
  10. Ivanova, A. S., Korneeva, E. V., Bukhtiyarova, G. A., et al. (2011). Hydrocracking of vacuum gas oil in the presence of supported nickel-tungsten catalysts. Kinetics and Catalysis, 52(3), 446–458.
  11. Bdwi, E. A. S., Ali, S. A., Quddus, M. R., et al. (2017). Kinetics of promotional effects of oil-soluble dispersed metal (Mo, Co, and Fe) catalysts on slurry phase hydrocracking of vacuum gas oil. Energy & Fuels, 31(3), 3132–3142.
  12. Dik, P. P., Klimov, O. V., Budukva, S. V., et al. (2014). Silica-alumina based nickel-molybdenum catalysts for vacuum gas oil hydrocracking aimed at a higher diesel fraction yield. Catalysis in Industry, 6(3), 231–238.
  13. Кazakov, М. О., Naedina, К. А., Кlimov, О. В., et al. (2016). Development of new home catalysts for deep hydroprocessing of vacuum gas oil. Advanced Catalysts and Technologies, 16(6), 85-93.
  14. Halmenschlager, C. M., Brar, M., Apan, I. T., Klerk, A. (2019). Hydrocracking vacuum gas oil with wax. Catalysis Today, 353, 187-196.
  15. Dik, P. P., Pereima, V. Y., Nadeina, K. A., et al. (2018). Hydrocracking of vacuum gasoil on NiMoW/AAS-Al2O3 trimetallic catalysts: Effect of the W : Mo ratio. Catalysis in Industry, 10, 20–28.
  16. Dik, P. P., Danilova, I. G., Golubeva, I. S., et al. (2019). Hydrocracking of vacuum gas oil over NiMo/zeolite-Al2O3: Influence of zeolite properties. Fuel, 237, 178-190.
  17. Camblor, M. A., Corma, A., Martı́nez, A., et al. (1998). Mild hydrocracking of vacuum gasoil over NiMo-beta zeolite catalysts: The role of the location of the NiMo phases and the crystallite size of the zeolite. Journal of Catalysis, 179(2), 537–547.
  18. Taufiqurrahmi, N., Mohamed, A. R., Bhatia, S. (2011). Nanocrystalline zeolite beta and zeolite Y as catalysts in used palm oil cracking for the production of biofuel. Journal of Nanoparticle Research, 13(8), 3177–3189.
  19. Faraji, D., Sadighi, S., Mazaheri, H. (2017). Modeling and evaluating zeolite and amorphous based catalysts in vacuum gas oil hydrocracking process. International Journal of Chemical Reactor Engineering, 16(1), 1-14.
  20. Wei, Q., Zhang, J., Liu, X., et al. (2019). Citric acid-treated zeolite Y (CY)/Zeolite beta composites as supports for vacuum gas oil hydrocracking catalysts: High yield production of highly-aromatic heavy naphtha and low-BMCI value tail oil. Frontiers in Chemistry, 7, 00705.
  21. Cui, Q., Zhou, Y., Wei, Q., et al. (2012). Role of the zeolite crystallite size on hydrocracking of vacuum gas oil over NiW/Y-ASA catalysts. Energy & Fuels, 26(8), 4664–4670.
  22. Henry, R., Tayakout-Fayolle, M., Afanasiev, P., et al. (2014). Vacuum gas oil hydrocracking performance of bifunctional Mo/Y zeolite catalysts in a semi-batch reactor. Catalysis Today, 220-222, 159–167.
  23. Onishchenko, M. I., Kulikov, A. B., Maksimov, A. L. (2017). Application of zeolite Y-based Ni–W supported and in situ prepared catalysts in the process of vacuum gas oil hydrocracking. Petroleum Chemistry, 57(14), 1287–1294.
  24. Kazakov, M. O., Nadeina, K. A., Danilova, I. G., et al. (2018). Hydrocracking of vacuum gas oil over NiMo/Y-Al2O3. Effect of mesoporosity introduced by zeolite Y recrystallization. Catalysis Today, 305, 117–125.
  25. Abbasov, V., Mammadova, T., Aliyeva, N., et al. (2016). Catalytic cracking of vegetable oils and vacuum gasoil with commercial high alumina zeolite and halloysite nanotubes for biofuel production. Fuel, 181, 55−63.
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DOI: 10.5510/OGP20220300713

E-mail: gulbenizmuxtarova@yahoo.com


M. D. Ibragimova, S.A. Seidovа, S.G. Aliyevа, R.A.Dzhafarova, U. J. Yolchueva

Institute of Petrochemical Processes named after Y.H.Mammadaliyev, Azerbaijan National Academy of Sciences, Baku, Azerbaijan

Research of the residual content of aromatic hydrocarbons in the composition of diesel fuel after extraction cleaning


In paper the results of luminescent studies mixture of the straight-run diesel fraction with the product secondary oil refining — light gas oil coking at a mass ratio of components of 70:30% of the masses and raffinates obtained by extraction purification of the indicated feedstock with N-methylpyrrolidone and an ionic liquid - N-methylpyrrolidoneacetate synthesized based on N- methylpyrrolidone and acetic acid have been presented. A series of studies has established a relatively high extraction ability of the ionic liquid, compared with N-methylpyrrolidone. Since under similar conditions of selective purification using the specified ionic liquid as the extractant, bicyclic aromatic hydrocarbons are almost completely removed from the composition of the test mixture of the diesel fraction.

Keywords: raffinate; luminescent studies; extraction purification; UV spectral analysis; ionic liquid; N-methylpyrrolidone.

In paper the results of luminescent studies mixture of the straight-run diesel fraction with the product secondary oil refining — light gas oil coking at a mass ratio of components of 70:30% of the masses and raffinates obtained by extraction purification of the indicated feedstock with N-methylpyrrolidone and an ionic liquid - N-methylpyrrolidoneacetate synthesized based on N- methylpyrrolidone and acetic acid have been presented. A series of studies has established a relatively high extraction ability of the ionic liquid, compared with N-methylpyrrolidone. Since under similar conditions of selective purification using the specified ionic liquid as the extractant, bicyclic aromatic hydrocarbons are almost completely removed from the composition of the test mixture of the diesel fraction.

Keywords: raffinate; luminescent studies; extraction purification; UV spectral analysis; ionic liquid; N-methylpyrrolidone.

References

  1. Bukhtiyarova, G. A., Vlasova, E. N., Aleksandrov, P. V., et al. (2016). Hydroupgrading of mixtures of straight-run diesel fraction and light catcracking gasoil using a nimo sulfide catalyst on a zeolite-containing support. Kataliz v promyshlennosti, 6, 23-32.
  2. Kameshkov, A. V., Gayle, A. A., Smirnova, D. A., et al. (2018). Combined extraction-hydrogenation processes of diesel and marine fuels production. Oil Processing and Petrochemistry, 5, 3-6.
  3. Solmanov, P. S., Maximov, N. M., Eremina, Yu. V., et al. (2013). Hydrotreating of mixtures of diesel fractions with gasoline and light coker gas oil. Petroleum Chemistry, 53(3), 177-180.
  4. Kolbin, V. A., Dezortsev, S. V., Telyashev, E. G. (2016). Ekstraktsionnoye oblagorazhivaniye tyazhelogo komponenta dizel'nogo topliva N-metilpirrolidonom. Bashkirskiy Khimicheskiy Zhurnal, 2016, 23(1), 3-6.
  5. Gayle, A. A., Zalishchevskiy, G. D., Semenov, L. V. (2004). Ekstraktsionnaya ochistka pryamogonnoy dizel'noy fraktsii ot seroorganicheskikh soyedineniy i aromaticheskikh uglevodorodov. Neftepererabotka i Neftekhimiya, 1, 23-27.
  6. Liu, J., Gui, L., Song, X. (2008). Deep desulfurization of diesel fuel by extraction with task-specific ionic liquids. Journal Petroleum Science and Technology, 26, 973-982
  7. Swapnil, A., Dharaskar, K. L., Wasewar, M. N. (2014). Extractive desulfurization of liquid fuels by energy efficient green thiazolium based ionic liquids. Industrial & Engineering Chemistry, 53(51), 19845–19854.
  8. Teng-Jie, R., Juan, Z., Yan-Hui, H., et al. (2015). Extractive desulfurization of fuel oil with metal-based ionic liquids. Chinese Chemical Letters, 26(9), 1169-1173.
  9. Azizov, A. G., Ibragimova, M. D., Gasanova, R. Z., Guseinova, A. D. (2008). Ion-liquid treatment of oil fractions. Azerbaijan Oil Industry, 7, 64-68.
  10. Azizov, A. G., Guseynova, A. D., Ibragimova, M. D. i dr. (2007). Primeneniye ionnykh zhidkostey v protsesse polucheniya vysokokachestvennykh ekologicheski chistykh avtomobil'nykh benzinov. Neftepererabotka i Neftekhimiya, 6, 25.
  11. Seidova, S. A., Guseynov, G. D., Nagiyev, V. A., et al. (2017). Ecologically clean diesel fuel received by the ionic-liquid extraction method. Baku Engineering University Chemistry and Biology, 1(2), 216-221.
  12. Ibragimova, M. D., Seidova, S. A., Guseynov, G. Dz., et al. (2018). Study of structurally-group composition of raffinate and extract obtained by dearomatizing of a mix of once-run diesel fraction with products of the secondary petroleum refining. Oil Processing and Petrochemistry, 8, 14-20.
  13. Mamedov, A. P., Dzhafarova, R. A., Nadzhafova, M. A., Salmanova, CH. K. (2014). Spektral'no-lyuminestsentnyye svoystva, EPR i fotokhimiya nefteproduktov. Baku: «Elm».
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DOI: 10.5510/OGP20220300714

E-mail: minaver-ibrahimova@rambler.ru


L. M. Gaisina1, I. L. Litvinenko2, L. R. Magomaeva3, A. A. Agayev4

1Ufa State Petroleum Technological University, Ufa, Russia; 2Moscow State University of Humanities and Economics, Moscow, Russia; 3Grozny State Oil Technical University named after Academician M.D. Millionshchikov, Grozny, Russia; 4Sumgait State University, Sumgait, Azerbaijan

Impact of the pandemic and the green economy on the development of the oil and gas sector


The article examines the impact of the most significant factors in the global economic transformation - the pandemic and the «green» economy on the development of the oil and gas sector. The development trends of the global oil and gas sector in the pre-pandemic period were identified, the most significant changes in its development in the period 2019-2021 were identi-fied, which of these changes were most due to the impact of the Covid-19 pandemic, which were due to the influence of the «green» economy, changes that have arisen independently of these two factors are indicated. The forecasts for the development of the oil and gas sector in the con-text of the risks associated with the development of the «green» economy and the consequences of the Covid-19 pandemic in the short, medium and long term have been studied. Significant at-tention is paid to the issues related to the differentiation of long-term and short-term trends in the development of the oil and gas industry under the influence of these two system-forming fac-tors. The article also explored the strategic prospects for the development of the oil and gas in-dustry as an alternative to the «green» economy, revealed. What impact will the Covid-19 pan-demic presumably have in terms of confrontation between traditional oil and gas energy and green energy as a possible main energy of the future. The geographic features of the energy trans-formation are determined, the regions are identified, the development of the oil and gas sector of which is affected by the coronavirus pandemic and the «green» economy in different ways.

Keywords: oil and gas sector; Covid-19 pandemic; green economy; global economy; sectoral economy; global markets.

The article examines the impact of the most significant factors in the global economic transformation - the pandemic and the «green» economy on the development of the oil and gas sector. The development trends of the global oil and gas sector in the pre-pandemic period were identified, the most significant changes in its development in the period 2019-2021 were identi-fied, which of these changes were most due to the impact of the Covid-19 pandemic, which were due to the influence of the «green» economy, changes that have arisen independently of these two factors are indicated. The forecasts for the development of the oil and gas sector in the con-text of the risks associated with the development of the «green» economy and the consequences of the Covid-19 pandemic in the short, medium and long term have been studied. Significant at-tention is paid to the issues related to the differentiation of long-term and short-term trends in the development of the oil and gas industry under the influence of these two system-forming fac-tors. The article also explored the strategic prospects for the development of the oil and gas in-dustry as an alternative to the «green» economy, revealed. What impact will the Covid-19 pan-demic presumably have in terms of confrontation between traditional oil and gas energy and green energy as a possible main energy of the future. The geographic features of the energy trans-formation are determined, the regions are identified, the development of the oil and gas sector of which is affected by the coronavirus pandemic and the «green» economy in different ways.

Keywords: oil and gas sector; Covid-19 pandemic; green economy; global economy; sectoral economy; global markets.

References

  1. Gaisina L. M., Shayakhmetova R. R., Mingazetdinova R. F., et al. (2021). Social responsibility during the Covid-19 Pandemic (The Republic of Bashkortostan). Laplage em Revista, 7(3A), 226-234.
  2. Bakhtizin, R., Evtushenko, E., Burenina, I., et al. (2016). Methodical approach to design of system of the logistic centers and wholesale warehouses at the regional level. Journal of Advanced Research in Law and Economics, 1(15), 16–25.
  3. Gaisina, L. M., Bakhtizin, R. N., Mikhaylovskaya, I. M., et al. (2015). Sociological evaluation of effectiveness of labor workers’ behavior. Biosciences, Biotechnology Research Asia, 12(3), 3091-3100.
  4. Aloui, D., Goutte, S., Hchaichi, R. (2020). COVID 19’s impact on crude oil and natural gas S&P GS Indexes. HAL SHS. https://halshs.archives-ouvertes.fr/halshs-02613280
  5. Dmytrów, K., Landmesser, J., Bieszk-Stolorz, B. (2021).The connections between COVID-19 and the energy commodities prices: Evidence through the dynamic time warping method. Energies, 14, 4024.
  6. Mugaloglu, E., Polat, A. Y., Tekin, H., Dogan, A. (2021). Oil price shocks during the COVID-19 pandemic: Evidence from United Kingdom energy stocks. Energy Research Letters, 2(1). https://doi.org/10.46557/001c.24253
  7. (2020). OECD Policy Responses to Coronavirus (COVID-19).The impact of coronavirus (COVID-19) and the global oil price shock on the fiscal position of oil-exporting devel-oping countries. https://read.oecd.org/10.1787/8bafbd95-en?format=pdf
  8. Prabheesh, K. P., Padhan, R., Garg, B. (2020). COVID-19 and the oil price–stock market nexus: Evidence from net oilimporting countries. Energy Research Letters, 1(2).
  9. Nyga-Łukaszewska, H., Aruga, K. (2020). Energy prices and COVID-immunity: The case of crude oil and natural gas prices in the US and Japan. Energies, 13, 6300.
  10. Salisu, A. A., Ebuh, G. U., Usman, N. (2020). Revisiting oil-stock nexus during COVID-19 pandemic: Some preliminary results. International Review of Economics & Finance, 69, 280–294.
  11. Indupurnahayu, I., Setiawan, E. B., Agusinta, L., et al. (2021). Changes in demand and supply of the crude oil market during the COVID-19 pandemic and its effects on the natural gas market. International Journal of Energy Economics and Policy, 11(3), 1–6.
  12. Kasztelan, A. (2017). Green growth, green economy and sustainable development: Terminological and relational discourse. Prague Economic Papers, 26, 487-499.
  13. D'Amato, D., Korhonen, J. (2021). Integrating the green economy, circular economy and bioeconomy in a strategic sustainability framework. Ecological Economics, 188, 107143.
  14. Ahmad, T., Zhang, D. (2020). A critical review of comparative global historical energy consumption and future demand: The story told so far. Energy Reports, 6, 1973-1991.
  15. Timokhin, D., Bugaenko, M., Putilov, A. (2020). The use of IT technologies in the implementation of the «economic cross» methodology in the «Breakthrough» project of Rosatom. Procedia Computer Science, 169, 445-451.
  16. Gromova, E., Timokhin, D., Popova, G. (2020). The role of digitalisation in the economy development of small innovative enterprises. Procedia Computer Science, 169, 461-467.
  17. Litvinenko, I. L., Gaisina, L. M., Semenova, L., et al. (2021). Transformation of institutions of socio-economic development in the conditions of a long-term viral pandemic. AD ALTA: Journal of Interdisciplinary Research, 11(2), S21, 220-224.
  18. Litvinenko, I., Gaisina, L., Shakirova, E., et al. (2021). An innovative component of widespread digitalization: Scopes and perspectives. AD ALTA: Journal of Interdisciplinary Research, 11(2), S21, 225-230.
  19. Kumar, M. (2020). Social, economic, and environmental impacts of renewable en-ergy resources /in K. E. Okedu, A. Tahour, A. G. Aissaou (Eds.). Wind solar hybrid renewable energy system. IntechOpen.
  20. Fulwood, M. S. (2022). Surging 2021 European gas prices – Why and how? Oxford: The Oxford Institute for Energy Studies.
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  22. Revel-Muroz, P. A., Bakhtizin, R. N., Karimov, R. M., Mastobaev, B. N. (2017). Joint use of thermal and chemical methods of exposure during transportation of high-viscosity and solidifying oils. SOCAR Proceedings, 2, 49-55.
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  24. Gorokhova, A. E., Gaisina, L. M., Gareev, E. S., et al. (2018). Application of coaching methods at agricultural and industrial enterprises to improve the quality of young spe-cialists’ adaptation. Quality - Access to Success, 19(164), 103-108.
  25. Sekerin, V. D., Gaisina, L. M., Shutov, N. V., et al. (2018). Improving the quality of competence-oriented training of personnel at industrial enterprises. Quality - Access to Success, 19(165), 68-72.
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DOI: 10.5510/OGP20220300715

E-mail: glmug@mail.ru


А. К. Маzitоvа, G. К. Аminovа, I. N. Vikharevа

Ufa State Petroleum Technological University, Ufа, Russia

Development of new environmentally friendly plasticizers


A significant expansion of the range of polymer materials is associated with the constant improvement of technological processes for the production of polymer products, the quality of raw materials, the use of new additives to ensure the necessary consumer characteristics of products. Currently, due to the deterioration of the environmental situation associated with an increase in the amount of plastic waste, it is urgent to develop environmentally friendly additives that provide technical and operational characteristics for a certain period of operation, and then accelerate biodegradation in the environment. This paper considers the synthesis of a number of new environmentally friendly plasticizers based on adipic acid and aliphatic alcohols of normal and iso-structure C4-C10. The study of their physical and chemical characteristics showed the possibility of their practical use as PVC plasticizers. The tests carried out confirmed the good compatibility of the developed additives with polyvinyl chloride. The study of the glass transition temperature of the obtained samples of PVC compositions using the obtained plasticizers showed the high efficiency of their plasticizing action.

Keywords: adipate plasticizer; compatibility; efficiency; environmentally friendly; esterification; polyvinyl chloride.

A significant expansion of the range of polymer materials is associated with the constant improvement of technological processes for the production of polymer products, the quality of raw materials, the use of new additives to ensure the necessary consumer characteristics of products. Currently, due to the deterioration of the environmental situation associated with an increase in the amount of plastic waste, it is urgent to develop environmentally friendly additives that provide technical and operational characteristics for a certain period of operation, and then accelerate biodegradation in the environment. This paper considers the synthesis of a number of new environmentally friendly plasticizers based on adipic acid and aliphatic alcohols of normal and iso-structure C4-C10. The study of their physical and chemical characteristics showed the possibility of their practical use as PVC plasticizers. The tests carried out confirmed the good compatibility of the developed additives with polyvinyl chloride. The study of the glass transition temperature of the obtained samples of PVC compositions using the obtained plasticizers showed the high efficiency of their plasticizing action.

Keywords: adipate plasticizer; compatibility; efficiency; environmentally friendly; esterification; polyvinyl chloride.

References

  1. La Mantia, F., Morreale, M. (2011). Green composites: A brief review. Composites Part A: Applied Science and Manufacturing, 42, 579–588.
  2. Mohanty, A. K., Misra, M., Drzal, L. (2002). Sustainable bio-composites from renewable resources: Opportunities and challenges in the green materials world. Journal of Polymers and the Environment, 10, 19–26.
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  5. Dadashov, I. F., Loboichenko, V. M., Strelets, V. M., et al. (2020). About the environmental characteristics of fire extinguishing substances used in extinguishing oil and petroleum products. SOCAR Proceedings, 1, 79-84.
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DOI: 10.5510/OGP20220300716

E-mail: irina.vikhareva2009@yandex.ru